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Selective growth of vertically aligned double- and single-walled carbon nanotubes on a substrate at 590 degrees C

机译:垂直取向的双壁和单壁碳纳米管在590摄氏度下在衬底上的选择性生长

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摘要

Vertically aligned double- and single-walled carbon nanotubes (DWNTs and SWNTs) were synthesized on a substrate at 590 degrees C by hot-filament chemical vapor deposition. An optimized combination of iron and aluminum layers as the catalyst resulted in iron particles ranging from 1-5 nm floating in an aluminum matrix after annealing. Selective synthesis of DWNTs and SWNTs from such particles was achieved by adjusting the dilution ratio of acetylene that was used as the source gas. The yield of DWNTs among all CNTs was as high as 81%, while that of SWNTs was almost 100%. The diameter distribution of DWNTs was narrow, with a standard deviation of about 12%.
机译:通过热丝化学气相沉积法在590摄氏度的基板上合成了垂直排列的双壁和单壁碳纳米管(DWNT和SWNT)。铁层和铝层作为催化剂的优化组合导致退火后漂浮在铝基质中的1-5 nm的铁颗粒。通过调节用作原料气的乙炔的稀释比例,可以从此类颗粒中选择性合成DWNT和SWNT。所有CNT中DWNT的产率高达81%,而SWNT的产率几乎为100%。 DWNT的直径分布较窄,标准偏差约为12%。

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