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Selective self-alignment of Au nanoparticle-coated K_2SO_4 microcrystals in micrometre gratings of V-grooves on a silicon substrate

机译:硅基底上V型槽的微米光栅中Au纳米颗粒包覆的K_2SO_4微晶的选择性自对准

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摘要

Gold-nanoparticle-coated K_2SO_4 microcrystals were prepared by a recently reported self-assembly process and their organization onto micron-patterned silicon substrates was explored. Electron beam lithography, anisotropic chemical etching and high temperature thermal oxidation were used to fabricate oxidized or non-oxidized V-grooves on a silicon substrate and suspensions of gold-coated microcrystals were spin-coated over the surface. The nanoparticle-coated microcrystals were found to spontaneously deposit within the grooves and to form remarkably coherent structures made up of lines of microcrystals aligned relative to each other. Controls showed that this phenomenon was not observed with bare K_2SO_4 crystals suggesting a catalytic role for the gold nanoparticles in the organization process.
机译:通过最近报道的自组装工艺制备了纳米金包覆的K_2SO_4微晶,并探索了它们在微米图案化的硅衬底上的组织。电子束光刻,各向异性化学刻蚀和高温热氧化被用来在硅衬底上制造氧化或未氧化的V型槽,并在表面上旋涂金包被的微晶悬浮液。发现涂覆有纳米颗粒的微晶自发地沉积在凹槽内并形成由彼此相对排列的微晶线组成的明显相干的结构。对照表明,用裸露的K_2SO_4晶体未观察到此现象,表明金纳米颗粒在组织过程中起催化作用。

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