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Backbone-induced effects in the charge transport efficiency of synthetic DNA molecules

机译:骨干对合成DNA分子的电荷传输效率的影响

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We report on a theoretical study pointing out the fundamental role of the backbone energetics in the charge transfer efficiency of polyG-polyC and polyA-polyT chains. The double-strand DNA (ds-DNA) molecules are modelled in terms of a single channel effective Hamiltonian. By introducing a two-step renormalization scheme analytical results for the energy spectrum and transmission coefficient are derived, and current-voltage characteristics are numerically investigated. Significant modulations of the main I-V features (voltage threshold, current amplitude) are reported and their physical origin is traced back to backbone-induced electronic effects. These results open new perspectives for experimental work aimed at controlling the charge transfer efficiency in nanodevices based on synthetic DNA.
机译:我们报告了一项理论研究,指出了骨架能量学在polyG-polyC和polyA-polyT链的电荷转移效率中的基本作用。根据单通道有效哈密顿量对双链DNA(ds-DNA)分子进行建模。通过引入两步重归一化方案,得出了能谱和传输系数的分析结果,并对电流-电压特性进行了数值研究。报告了主要I-V特征(电压阈值,电流幅度)的重大调制,其物理起源可追溯到主干诱导的电子效应。这些结果为旨在控制基于合成DNA的纳米器件中电荷转移效率的实验工作开辟了新的前景。

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