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The effects of an inserted linear carbon chain on the vibration of a carbon nanotube

机译:插入的线性碳链对碳纳米管振动的影响

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An elastic string-elastic shell model is developed to study the coupled vibration of a carbon nanowire made of a linear carbon chain (C-chain) inserted inside a carbon nanotube (CNT). It is shown that the vibration of the inserted C-chain is coupled with vibration of the CNT only for vibration modes with circumferential wavenumber n = 1. In other cases, such as axisymmetric modes (n = 0) or higher-order vibration modes with n > = 2, total resultant van der Waals (vdW) force acting on the C-chain due to the innermost tube always vanishes, and therefore vibration of the CNT does not cause vibration of the inserted C-chain, although the existence of the C-chain does have an effect on the vibration of the CNT through the chain-CNT vdW forces acting on the innermost tube. The present model predicts that non-coaxial vibration between the C-chain and the innermost tube does not occur due to negligible bending rigidity of the C-chain. In addition, it is found that the C-chain has most significant effect on the lowest frequency associated with the radial vibration mode for circumferential wavenumber 2 (n = 2). In particular, the effect of the C-chain on the axisymmetric radial breathing frequencies (n = 0) predicted by the present model is found to be in reasonable agreement with known experimental and modeling results available in the literature. The present work offers systematic modeling results on the effects of an inserted C-chain on the vibration of CNTs.
机译:开发了弹性线-弹壳模型来研究由插入碳纳米管(CNT)内的线性碳链(C链)制成的碳纳米线的耦合振动。结果表明,插入的C链的振动仅与圆周波数为n = 1的振动模式与CNT的振动耦合。在其他情况下,例如轴对称模式(n = 0)或具有n> = 2,由于最里面的管作用在C链上的总合力范德华力(vdW)始终消失,因此,尽管存在碳纳米管,但CNT的振动不会引起插入的C链的振动。 C链确实通过作用在最内管上的CNT-CNT vdW力对CNT的振动产生影响。本模型预测,由于C链的抗弯刚度可忽略不计,因此C链与最内管之间不会发生非同轴振动。另外,对于圆周波数2(n = 2),发现C链对与径向振动模式相关的最低频率影响最大。特别地,发现本发明模型预测的C链对轴对称径向呼吸频率(n = 0)的影响与文献中已知的已知实验和建模结果合理地一致。本工作提供了关于插入的C链对CNT振动影响的系统建模结果。

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