Self-assembled polyaniline nanotubes grown from a polymeric acid solution

Lijuan Zhang; Hui Peng; Chyong Fang Hsu

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Self-assembled polyaniline nanotubes grown from a polymeric acid solution

机译：从聚合酸溶液中生长的自组装聚苯胺纳米管

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Polyaniline (PANI) nanotubes were obtained by a self-assembly process, from a solution coutaining poly(methyl vinyl ether-alt-maleic acid) (PMVEA) by oxidative polymerization using ammonium persulfate as the oxidant. The size of (he nanotubes was greatly affected by the weight ratio of polymeric acid to aniline as measured by SEM images. The outer diameter of the nanotubes increased from 65 to 160 nm as the weight ratio of PMVEA to aniline increased from 1 to 4 wt/wt percent. The structural features of the nanotubes were eharaclerized by FTIR, XPS and EPR spectroscopies, which confirmed the presence of the polymeric acid in the PANI nanotubes and their electronic conductive nature. The electrochemical properties were further analysed using cyclic voltammetry.

机译：聚苯胺（PANI）纳米管是通过自组装工艺从使用过硫酸铵作为氧化剂通过氧化聚合而得的聚甲基乙烯醚-马来酸马来酸（PMVEA）溶液中获得的。通过SEM图像测量，纳米管的尺寸受聚合酸与苯胺的重量比的影响很大。随着PMVEA与苯胺的重量比从1到4 wt％，纳米管的外径从65 nm增加到160 nm。 FTIR，XPS和EPR光谱法证实了纳米管的结构特征，证实了PANI纳米管中存在聚合酸及其导电性，并使用循环伏安法进一步分析了电化学性能。

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《Nanotechnology》 |2007年第11期|共6页
作者
Lijuan Zhang; Hui Peng; Chyong Fang Hsu;
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正文语种 eng
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1. Self-assembled polyaniline nanotubes grown from a polymeric acid solution [J] . Lijuan Zhang, Hui Peng, Chyong Fang Hsu Nanotechnology . 2007,第11期

机译：从聚合酸溶液中生长的自组装聚苯胺纳米管
2. Self-assembled polyaniline nanotubes grown from a polymeric acid solution - art. no. 115607 [J] . Zhang LJ, Peng H, Hsu CF, Nanotechnology . 2007,第11期

机译：从聚合酸溶液中生长的自组装聚苯胺纳米管-艺术。没有。 115607
3. Exploration of the morphological transition phenomenon of polyaniline from microspheres to nanotubes in acid-free aqueous 1 -propanol solution in a single polymerization process [J] . Yu-Fong Huang, Chi-Wen Lin Polymer international . 2010,第9期

机译：单一聚合过程中无酸1-丙醇水溶液中聚苯胺从微球到纳米管形态转变现象的探索
4. INTERFACIAL INHIBITIVE EFFECT OF POLYANILINE METANILIC ACID CO-POLYMER ON MILD STEEL FOR ACID RAIN SOLUTION [C] . K.S.Ranga krishnan, P.Rajakumar, S.Pitchumani 201st Meeting of the Electrochemical Society: Meeting Abstracts Volume 2002-1, May 12-17, 2002, Philadelphia, PA, USA . 2002

机译：聚苯胺甲基丙烯酸共聚合物对软钢在酸雨溶液中的界面抑制作用
5. Bio-templated conducting polymer nanostructures for sensitive detection and flexible electronics: I. DNA-templated polyaniline nanowire for fast detection of chemicals. II. A self-doped polyaniline/carbon nanotube nanocomposite for ultrasensitive biosensors and flexible electronics [D] . Ma, Yufeng 2007

机译：用于灵敏检测和柔性电子的生物模板导电聚合物纳米结构：I. DNA模板聚苯胺纳米线，用于快速检测化学物质。二。用于超灵敏生物传感器和柔性电子产品的自掺杂聚苯胺/碳纳米管纳米复合材料
6. Oriented Polyaniline Nanowire Arrays Grown on Dendrimer (PAMAM) Functionalized Multiwalled Carbon Nanotubes as Supercapacitor Electrode Materials [O] . Lin Jin, Yu Jiang, Mengjie Zhang, -1

机译：树枝状大分子（PAMAM）功能化的多壁碳纳米管上生长的定向聚苯胺纳米线阵列作为超级电容器电极材料
7. Synthesis and Electrical Properties of Polyaniline/Polyaniline Grafted Multiwalled Carbon Nanotube Mixture via Suspension Polymerization [O] . Kang Sang-Wook 2010

机译：悬浮聚合制备聚苯胺/聚苯胺接枝多壁碳纳米管混合物及其电性能
8. Synthesis and Electrical Properties of Polyaniline/Polyaniline Grafted Multiwalled Carbon Nanotube Mixture via In Situ Static Interfacial Polymerization. [R] . Jeon, I., Tan, L., Baek, J. 2010

机译：聚苯胺/聚苯胺接枝多壁碳纳米管混合物的原位静态界面聚合及电性能。

Self-assembled polyaniline nanotubes grown from a polymeric acid solution

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