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Electronic conduction processes in DNA-doped polypyrrole nanocomposite films

机译:DNA掺杂的聚吡咯纳米复合薄膜中的电子传导过程

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摘要

The electron transport process in DNA-doped polypyrrole (PPY) nanocomposite film deposited on tin oxide coated glass by a simple electrodeposition technique is demonstrated here. Optical absorbance spectra clearly exhibited features corresponding to doped PPY nanocomposite film. The I-V characteristics of the films were non-ohmic and showed a significant change when illuminated with light. Photoinduced I-V profiles suggested carrier hopping to be the dominant transport mechanism in the nanocomposite PPY film. The temperature-dependent dc electrical conductivity data showed a crossover from variable-range hopping to thermally activated hopping of electrons with the increase in temperature. The ac electrical transport properties displayed a frequency-independent region below a characteristic frequency of approx 400 kHz, above which the conductivity showed a strong frequency-dependent behaviour.
机译:本文介绍了通过简单的电沉积技术沉积在氧化锡涂层玻璃上的DNA掺杂的聚吡咯(PPY)纳米复合膜中的电子传输过程。光吸收光谱清楚地表现出对应于掺杂的PPY纳米复合膜的特征。膜的I-V特性是非欧姆性的,当用光照射时显示出明显的变化。光诱导的I-V曲线表明载流子跳跃是纳米复合PPY膜的主要传输机制。温度相关的直流电导率数据显示,随着温度的升高,电子从可变范围跳跃跃迁到热激活跳跃。交流电传输特性在低于约400 kHz的特征频率以下显示了一个与频率无关的区域,在该区域之上,电导率表现出很强的与频率相关的行为。

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