Controlled synthesis and morphology dependent upconversion luminescence of NaYF4 : Yb, Er nanocrystals

Sun YJ; Chen Y; Tian LJ; Yu Y; Kong XG; Zhao JW; Zhang H

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Controlled synthesis and morphology dependent upconversion luminescence of NaYF4 : Yb, Er nanocrystals

机译：NaYF4：Yb，Er纳米晶的受控合成和依赖形态的上转换发光

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Size and morphology controlled NaYF4:Yb, Er nanocrystals were synthesized via the hydrothermal method. Polydentate ligands, such as EDTA and citrate, were used in the synthesis of cubic and hexagonal Yb3+, Er3+ codoped NaYF4 nanocrystals as a means of controlling the size and morphology of the nanocrystals. Subsequently, the particle size was found to be dependent on the nucleation rate, which, in turn, was governed by the reactant concentration, molar ratio and choice of ligand. The phase transformation from cubic to hexagonal was found to be sensitive to reaction time and reactant concentration. The upconversion photoluminescence of the nanocrystals demonstrated morphology dependence, which provides a means to characterize their crystalline quality and structure.

机译：通过水热法合成了尺寸和形貌受控的NaYF4：Yb，Er纳米晶体。多齿配体，例如EDTA和柠檬酸盐，被用于合成立方和六边形Yb3 +，Er3 +共掺杂的NaYF4纳米晶体，作为控制纳米晶体尺寸和形态的一种手段。随后，发现粒度取决于成核速率，成核速率又取决于反应物浓度，摩尔比和配体的选择。发现从立方到六方的相变对反应时间和反应物浓度敏感。纳米晶体的上转换光致发光表现出形态学依赖性，这提供了表征其晶体质量和结构的手段。

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《Nanotechnology》 |2007年第27期|共9页
作者
Sun YJ; Chen Y; Tian LJ; Yu Y; Kong XG; Zhao JW; Zhang H;
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中图分类一般工业技术;
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CONVERTING PHOSPHOR REPORTERS; INFRARED QUANTUM COUNTERS; PHOTON AVALANCHE; PARTICLE-SIZE; SOLID-STATE; METAL IONS; YTTRIUM; CHEMISTRY; COMPLEX; GREEN;

机译：转换磷报告剂;红外量子计数器;光子雪崩;颗粒大小;固态;金属离子;钇;化学;络合物;绿色;

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1. Controlled synthesis and morphology dependent upconversion luminescence of NaYF4 : Yb, Er nanocrystals [J] . Sun YJ, Chen Y, Tian LJ, Nanotechnology . 2007,第27期

机译：NaYF4：Yb，Er纳米晶的受控合成和依赖形态的上转换发光
2. Controlled Synthesis of Monodisperse Hexagonal NaYF4:Yb/Er Nanocrystals with Ultrasmall Size and Enhanced Upconversion Luminescence [J] . Hui Li, Lei Xu, Guanying Chen Molecules . 2017,第12期

机译：具有超小尺寸和增强的上转换发光的单分散六角形NaYF4：Yb / Er纳米晶体的受控合成
3. Controlled Synthesis of Monodisperse Hexagonal NaYF4:Yb/Er Nanocrystals with Ultrasmall Size and Enhanced Upconversion Luminescence [J] . Li Hui, Xu Lei, Chen Guanying Molecules . 2017,第12期

机译：控制合成单分散六边形NayF4：Yb / ER纳米晶体，具有超大尺寸和增强的上变化发光
4. Dynamic Probing Particle Size, Shape and Core-Shell Structure Dependent Photophysical Properties of Yb~(3+),Er~(3+) Codoped NaYF4 Nanocrystals: Applications for Upconversion Bioimaging and Photodynamic Therapy Cancer Treatment [C] . Jingning Shan, Mruthunjaya Uddi, Nan Yao, AIChE annual meeting . 2010

机译：Yb〜（3 +），Er〜（3+）共掺杂的NaYF4纳米晶体的动态探测粒径，形状和核壳结构相关的光物理性质：在上转换生物成像和光动力疗法治疗癌症中的应用
5. Surface Plasmon Enhanced Upconversion Luminescence of Yb 3+/ Tm3+ and Yb3+/ Er3+ Systems Doped in NaYF4 on Au Nanopillar Arrays. [D] . Luu, Quoc Anh Nguyen. 2014

机译：金纳米柱阵列上掺入NaYF4的Yb 3 + / Tm3 +和Yb3 + / Er3 +系统的表面等离子体增强上转换发光。
6. Controlled Synthesis of Monodisperse Hexagonal NaYF4:Yb/Er Nanocrystals with Ultrasmall Size and Enhanced Upconversion Luminescence [O] . Hui Li, Lei Xu, Guanying Chen 2017

机译：具有超小尺寸和增强的上转换发光的单分散六角形NaYF4：Yb / Er纳米晶体的受控合成
7. Controlled Synthesis of Monodisperse Hexagonal NaYF4:Yb/Er Nanocrystals with Ultrasmall Size and Enhanced Upconversion Luminescence [O] . Hui Li, Lei Xu, Guanying Chen 2017

机译：可控合成具有超小尺寸和增强上转换发光的单分散六角形NaYF4：Yb / Er纳米晶

Controlled synthesis and morphology dependent upconversion luminescence of NaYF4 : Yb, Er nanocrystals

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