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Excimer laser ablation of a Pt target inwater: the observation of hollow particles

机译:水中铂靶的准分子激光烧蚀:空心颗粒的观察

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Microanoparticles were fabricated by pulsed-excimer-laser ablation of a Pt target in water. Three kinds of hollow Pt particles (coalesced by micrograins, assembled by nanocrystals or with smooth shells) were observed together with solid particles using different laser fluences (2.3–6.8 J cm2) and after 6000 laser shots. We propose that the hollow particles were formed on laser-produced bubbles which provided thermodynamically preferred nucleation sites and diffusion sinks for the laser-fabricated Pt clusters or particles. Although the hollow particles are a small proportion, the results have extended the scope of particles that pulsed-laser ablation in liquid can fabricate, and have enriched the mechanistic scenario of laser ablation and nanostructure formation in liquid.
机译:通过脉冲激子激光烧蚀水中的Pt靶材来制备微米/纳米颗粒。在使用6000次激光照射后,使用不同的激光通量(2.3–6.8 J cm2)观察到了三种中空的Pt颗粒(由微颗粒簇集,由纳米晶体组装而成或具有光滑的壳)以及固体颗粒。我们建议中空粒子形成在激光产生的气泡上,该气泡为激光制造的Pt团簇或粒子提供了热力学上优选的成核位置和扩散汇。尽管中空颗粒的比例很小,但结果扩大了脉冲激光烧蚀在液体中可以制造的颗粒范围,并丰富了液体中激光烧蚀和纳米结构形成的机理。

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