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High-resolution imaging of gold clusters on KBr(001) surfaces investigated by dynamic scanning force microscopy

机译:动态扫描力显微镜研究KBr(001)表面上金团簇的高分辨率成像

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Dynamic scanning force microscopy (dynamic SFM) images of (001) surfaces of KBr which have been prepared by cleavage and further decorated by nanometre-sized gold clusters in UHV are presented. During scanning we could achieve atomic resolution on the KBr substrate surface; however, the clusters mostly appeared as hemisphere-like or fuzzy objects exhibiting only a few details of their internal structure. We performed force spectroscopy measurements above single clusters which might point to a charging of the clusters. We anticipate that mainly a long-range electrostatic interaction between the cluster and the macroscopic tip apex determines the appearance of the clusters. Information on the interior of the clusters can be gained only for short tip-cluster distances in the presence of a short-range, chemical interaction between the cluster and the tip atoms closest to the surface.
机译:呈现了通过裂解制备的KBr(001)表面的动态扫描力显微镜(dynamic SFM)图像,并通过超高压中的纳米级金簇进一步修饰。在扫描过程中,我们可以在KBr衬底表面上获得原子分辨率;然而,这些星团大多以半球状或模糊物体的形式出现,仅显示其内部结构的一些细节。我们在单个星团上方进行了力谱测量,这可能表明这些星团带电。我们预计,簇和宏观尖端之间的长程静电相互作用主要决定簇的外观。在簇和最靠近表面的尖端原子之间存在短距离化学相互作用的情况下,仅对于短的尖端簇距离,可以获得簇内部的信息。

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