We propose a novel technique to fabricate a free-standing three-dimensional colloidal crystal by self-assembling the colloidal microspheres with controllable thickness from the air-liquid interface. Highly ordered three-dimensional colloidal crystals are formed by polymethylmethacrylate or polystyrene monodisperse microspheres. We also demonstrate the fabrication technique of the free-standing inversed opals by removing the microspheres using calcination. The free-standing colloidal crystal structures can be used for nano-photonic circuits, white-light LEDs or as a photocatalyst.
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