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Zinc oxalate nanorods: a convenient precursor to uniform nanoparticles of ZnO

机译:草酸锌纳米棒:ZnO均匀纳米颗粒的便捷前体

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Nanorods of zinc oxalate dihydrate have been synthesized using the reverse micellar route. These nanorods were decomposed at 450 deg C in air to obtain nanoparticles of zinc oxide. Transmission electron microscopy shows the nanorods to be 120 nm in diameter and 600 nm in length. The ZnO nanoparticles are 55 nm in diameter. The photoluminescence studies show two peaks at 370 and 403 nm which can be ascribed to free excitonic transition and donor-acceptor pair transition respectively. The temperature dependent PL intensity shows an anomalous non-monotonous temperature dependence probably due to two different optical processes.
机译:草酸锌二水合物的纳米棒已使用反胶束路线合成。这些纳米棒在空气中在450℃下分解以获得氧化锌的纳米颗粒。透射电子显微镜显示纳米棒的直径为120nm,长度为600nm。 ZnO纳米粒子的直径为55 nm。光致发光研究表明在370和403 nm处有两个峰,分别归因于自由激子​​跃迁和供体-受体对跃迁。与温度相关的PL强度显示异常的非单调温度相关性,可能是由于两种不同的光学过程。

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