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Layer-by-layer deposited multilayer films of water soluble polythiophene derivative and gold nanoparticles exhibiting photoresponsive properties

机译:表现出光响应特性的水溶性聚噻吩衍生物和金纳米颗粒的逐层沉积多层膜

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摘要

Multilayer films of poly( 3,4-(3',3'-dithienyloxy) propyltrimethylammonium bromide) ( P34TOPA) and 11-mercaptoundecanonate ( MUA) capped gold nanoparticles ( GNPs) have been fabricated by layer-by-layer ( LBL) deposition. These films exhibit enhanced photoresponsive properties in comparison with those of a monolayer of P34TOPA and MUA capped GNPs. The photocurrent densities increased linearly with the bilayer number ( 1-10) of the multilayer films, indicating a sufficient charge separation and transportation. The size effect of gold nanoparticles on the photoresponsive properties of the multilayer films is also discussed.
机译:聚(3,4-(3',3'-二噻吩氧基)丙基三甲基溴化铵)(P34TOPA)和11-巯基十一烷酸酯(MUA)包覆的金纳米颗粒(GNP)的多层膜已通过逐层(LBL)沉积制备。与单层P34TOPA和MUA封端​​的GNP相比,这些薄膜具有增强的光响应性。光电流密度随着多层膜的双层数(1-10)线性增加,表明足够的电荷分离和传输。还讨论了金纳米颗粒对多层膜光响应性能的尺寸效应。

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