Ring A Conformation of Aconine and Pseudaconine in CDCl_3

Hong-Ying Deng; Qiao-Hong Chen; Feng-Peng Wang

首页> 外文期刊>Natural product communications >Ring A Conformation of Aconine and Pseudaconine in CDCl_3

【24h】

Ring A Conformation of Aconine and Pseudaconine in CDCl_3

机译：在CDCl_3中环化Aconine和Pseudaconine构象

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

On the basis of intensive interpretation of the 'H NMR spectroscopic data, the ring A conformation of aconine (1) was speculated as twist boat in CDCl_3, and as chair or twist boat in acetone-d6 and pyridine-ds. The ring A of pseudaconine (2) adopts the chair conformation in CDCl_3, acetone-d_6, and pyridine-d_5. Accordingly, the boat conformation of ring A in these two diterpenoid alkaloids in CDCl_3 reported in the literature [1] should be revised. The difference in ~(13)C NMR data for the same compound (1 or 2) in two different solvents (CDCl_3, pyridine-d_5) can be attributed to solvent effects.

机译：基于对'1 H NMR光谱数据的深入解释，推测乌头碱（1）的A环构象在CDCl_3中为扭曲舟，在丙酮-d6和吡啶-ds中为椅子或扭曲舟。伪乌头碱（2）的环A在CDCl_3，丙酮-d_6和吡啶-d_5中采用椅子构象。因此，文献[1]中报道的这两种二萜生物碱在CDCl_3中的环A的舟状构象应该被修改。同一化合物（1或2）在两种不同溶剂（CDCl_3，吡啶-d_5）中的〜（13）C NMR数据差异可归因于溶剂效应。

著录项

来源
《Natural product communications》 |2014年第6期|共2页
作者
Hong-Ying Deng; Qiao-Hong Chen; Feng-Peng Wang;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类自然科学总论;
关键词
C_(19)-Diterpenoid alkaloid; Conformation; Aconine; Pseudaconine.;

机译：C_（19）-二萜生物碱;构象;乌头碱;伪乌头碱。;

相似文献

外文文献
中文文献
专利

1. Ring A Conformation of Aconine and Pseudaconine in CDCl_3 [J] . Hong-Ying Deng, Qiao-Hong Chen, Feng-Peng Wang Natural product communications . 2014,第6期

机译：在CDCl_3中环化Aconine和Pseudaconine构象
2. Conformation of silicon-containing rings Part 1. A conformational study on 1,3,5-trisilacyclohexane. Comparison of ab initio, semiempirical, and molecular mechanics calculations. Conformational energy surface of 1,3,5-trisilacyclohexane [J] . Ingvar Arnason, Gudjon K. Thorarinsson, Eberhard Matern Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 1998,第1期

机译：含硅环的构象第1部分。1,3,5-三硅环己烷的构象研究。从头算，半经验和分子力学计算的比较。 1,3,5-三硅环己烷的构象能面
3. Interplay of para- and diatropic ring currents [(anti)aromaticity] of macrocyclic rings subject to conformational influences, further annelation and hydrogenation of aromatic ring moieties [J] . Erich Kleinpeter, Andreas Koch, Stefanie Schulz, Tetrahedron . 2014,第48期

机译：大环的对-变径环和变径环电流[（反）芳香性]之间的相互作用受到构象的影响，芳香环部分的进一步成环和氢化
4. Potent cyclic angiotensin II analogues confirm the ring cluster conformation:implications in the design of AT1 non-peptide antagonists [C] . Nektariosa Giatas, Anastasia Zoga, Maria-Eleni Androutsou, European Peptide Symposium . 2002

机译：有效的循环血管紧张素II类似物证实了环形簇构象：在AT1非肽拮抗剂设计中的含义
5. Conformational and structural investigation of substituted hydrocarbons and ring compounds by vibrational and microwave spectroscopy. [D] . Deodhar, Bhushan Shripad. 2016

机译：通过振动和微波光谱对取代烃和环化合物进行构象和结构研究。
6. Probing Open Conformation of GroEL Rings by Cross-linking Reveals Single and Double Open Ring Structures of GroEL in ADP and ATP [O] . Tatsuya Nojima, Masasuke Yoshida 2009

机译：通过交联探测GroEL环的开环构象揭示了ADP和ATP中GroEL的单和双开环结构
7. A 400- and 600-MHz proton NMR conformational study on nucleoside cyclic 3',5' Pv-TBP systems. Conformational transmission induces diequatorial orientation of the 3',5'-dioxaphosphorinane ring in a nonchair conformation [O] . Niek L. H. L. Broeders, Leo H. Koole, Henk M. Buck 1990

机译：核苷环三元3'，5'PV-TBP系统的400-和600MHz质子NMR研究。构象传导在非脚本构象中诱导3'，5'-二恶英磷酸环的Diequatorial取向

Ring A Conformation of Aconine and Pseudaconine in CDCl_3

摘要

著录项

相似文献

相关主题

期刊订阅