Conversion of taxane glycosides to 10-deacetylbaccatin III.

Yang T; Li M; Chen JM

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Conversion of taxane glycosides to 10-deacetylbaccatin III.

机译：紫杉烷苷转化为10-脱乙酰浆果赤霉素III。

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10-Deacetylbaccatin III (10-DAB III) (2) was obtained by a series of treatment of a mixture of taxane glycosides (3, 4, and 5) without isolation before treatment. Since the taxane glycosides are isolated with paclitaxel from yew trees and can be found during the process of the production of paclitaxel, their conversion to 10-DAB III improves the total yield of paclitaxel (1) and docetaxel.

机译：通过对紫杉烷糖苷（3、4和5）的混合物进行一系列处理，无需分离即可得到10-脱乙酰浆果赤霉素III（10-DAB III）（2）。由于紫杉烷糖苷是用紫杉醇从紫杉中分离得到的，并且可以在紫杉醇的生产过程中发现，因此将其转化为10-DAB III可以提高紫杉醇（1）和多西紫杉醇的总产量。

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来源
《Natural product research》 |2006年第2期|共6页
作者
Yang T; Li M; Chen JM;
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正文语种 eng
中图分类数理科学和化学;
关键词
taxane; Glycosides; Paclitaxel; Dimethylaminoazobenzene; 10-deacetylbaccatine III; 糖苷类; 紫杉酚;

机译：taxane;Glycosides;Paclitaxel;Dimethylaminoazobenzene;10-deacetylbaccatine III;糖苷类;紫杉酚;

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1. Conversion of taxane glycosides to 10-deacetylbaccatin III. [J] . Yang T, Li M, Chen JM Natural product research . 2006,第2期

机译：紫杉烷苷转化为10-脱乙酰浆果赤霉素III。
2. Modification of Taxane A Ring via Manoeuvering of the C-11 Double Bond of 10-Deacetylbaccatin III to Get Novel Rearranged Taxoids [J] . Vaishali Chakraborty Manobjyoti Bordoloi Letters in Organic Chemistry . 2008,第8期

机译：通过操纵10-去乙酰浆果赤霉素III的C-11双键来修饰紫杉烷A环以获得新颖的重排紫杉醇
3. Modification of Taxane A Ring via Manoeuvering of the C-11 Double Bond of 10-Deacetylbaccatin III to Get Novel Rearranged Taxoids [J] . Chakraborty V, Bordoloi M Letters in organic chemistry . 2008,第8期

机译：通过操纵10-去乙酰浆果赤霉素III的C-11双键来修饰紫杉烷A环以获得新颖的重排紫杉醇
4. Pressurized Hot Water Extraction and Enzyme-Catalyzed Conversion of Polyphenolic Glycosides in Onion Waste [C] . Charlotta Turner, Pernilla Turner, Gunilla Jacobson, European Meeting on Supercritical Fluids Reactions, Materials and Natural Products Processing . 2005

机译：加压的热水萃取和氨基酚糖苷的酶催化转化在洋葱废物中
5. I. Sulfonium-mediated oxidative glycosylation of glycal donors for the synthesis of C(2)-hydroxy-beta-glycosides. II. Hypervalent iodine (III)-mediated oxidative glycosylation of glycal donors for the synthesis of C(2)-acyloxy-beta-glycosides. III. Efforts toward the synthesis of immunologic adjuvant QS-21A(api). [D] . Kim, Yong-Jae. 2003

机译：I.硫介导的葡萄糖供体的氧化糖基化反应，用于合成C（2）-羟基-β-糖苷。二。高价碘（III）介导的糖供体的氧化糖基化反应，用于合成C（2）-酰氧基-β-糖苷。三，致力于合成免疫佐剂QS-21A（api）。
6. Structural Identification and Conversion Analysis of Malonyl Isoflavonoid Glycosides in Astragali Radix by HPLC Coupled with ESI-Q TOF/MS [O] . Yunfeng Zheng, Weiping Duan, Jie Sun, 2019

机译：HPLC-ESI-Q TOF / MS联用对黄芪中丙二酸异黄酮苷的结构鉴定和转化分析
7. A New Method to Modify the C-4 Position of 10-Deacetylbaccatin III. [O] . Kouichi UOTO, Haruhiro TAKENOSHITA, Takashi ISHIYAMA, 1997

机译：一种修饰10-deaetylbaccatin III的C-4位置的新方法。

Conversion of taxane glycosides to 10-deacetylbaccatin III.

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