Composition of Surface Adsorbed Layer of TiOsub2/sub Stored in Ambient Air

V.S. Zakharenko; M.N. Lyulyukin; D.V. Kozlov

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Composition of Surface Adsorbed Layer of TiOsub2/sub Stored in Ambient Air

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The processes of dark, UV, and visible light promoted desorption of surface species were investigated for three different TiO2 samples: TiO2 prepared by dispersion of the titania single crystal, TiO2 prepared by combustion of a pyrotechnic mixture in air, and commercial TiO2 P25. The composition of the adsorbed layer was identified in the dark and under UV and visible light irradiation. The composition of desorption products showed the dependence of the adsorption layer state on the TiO2 nature. Methane photodesorption was detected only for the commercial TiO2 P25. Possible reasons for methane emission include the capturing of complete molecules during the TiO2 production process and photocatalytic hydrogenation of CO2 under UV-light.

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《Catalysis for Sustainable Energy》 |2017年第1期|共6页
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V.S. Zakharenko; M.N. Lyulyukin; D.V. Kozlov;
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Composition of Surface Adsorbed Layer of TiOsub2/sub Stored in Ambient Air

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