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Derivatizing L-histidine to develop a novel additive for a polyol-based biolubricant

机译:衍生化L-组氨酸以开发用于多元醇基生物润滑剂的新型添加剂

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摘要

Two novel histidine Schiff base esters, HSE-A and HSE-B, were synthesized using a two-step reaction. The synthesized compounds were characterized using carbon, hydrogen, nitrogen analysis, Fourier-transform infrared and nuclear magnetic resonance spectroscopy. The antioxidant and anticorrosion properties of these additives were assessed using the universal oxidation test (IP-306) and standard accelerated corrosion testing procedure, which revealed that both additives have good antioxidant and anticorrosion properties. Lubricity test carried out in a four-ball test machine indicated that both additives could reduce wear when compared with the pure polyol base oil. Overall, the HSE-A additive is more effective than the HSE-B additive as an antioxidant/antiwear/anticorrosion biolubricant additive.
机译:使用两步反应合成了两种新型的组氨酸席夫碱酯HSE-A和HSE-B。使用碳,氢,氮分析,傅立叶变换红外光谱和核磁共振光谱对合成的化合物进行表征。使用通用氧化测试(IP-306)和标准加速腐蚀测试程序评估了这些添加剂的抗氧化和防腐性能,这表明两种添加剂均具有良好的抗氧化和防腐性能。在四球试验机中进行的润滑性测试表明,与纯多元醇基础油相比,两种添加剂均可减少磨损。总体而言,HSE-A添加剂作为抗氧化剂/抗磨/抗腐蚀生物润滑剂添加剂比HSE-B添加剂更有效。

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