Electrocatalytic activity of a polypyridyl ruthenium-oxo complex covalently attached to a graphite felt electrode

Florence Geneste; Claude Moinet

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Electrocatalytic activity of a polypyridyl ruthenium-oxo complex covalently attached to a graphite felt electrode

机译：共价结合到石墨毡电极上的聚吡啶钌-氧配合物的电催化活性

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The complex [Ru~(IV)(tpy)(bpy)(O)]~(2+) grafted to a graphite felt electrode shows electrocatalytic activity toward primary and secondary alcohols.Kinetic analyses highlights the contribution of the immobilized catalyst to the oxidation of benzenemethanol to the corresponding aldehyde,whereas the formation of benzoic acid from benzaldehyde is mostly due to a direct oxidation at the graphite electrode.In contrast to the catalyst in solution,the immobilized catalyst exhibits poor activity toward compounds containing C-H bonds adjacent to unsaturated bonds.

机译：接枝到石墨毡电极上的复合物[Ru〜（IV）（tpy）（bpy）（O）]〜（2+）对伯醇和仲醇表现出电催化活性。动力学分析突出了固定化催化剂对氧化的贡献苯甲醇转化为相应的醛，而苯甲醛生成苯甲酸的主要原因是石墨电极上的直接氧化。与溶液中的催化剂相比，固定化催化剂对含不饱和键附近的CH键的化合物的活性较弱。

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《New Journal of Chemistry》 |2004年第6期|共5页
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Florence Geneste; Claude Moinet;
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1. Electrocatalytic activity of a polypyridyl ruthenium-oxo complex covalently attached to a graphite felt electrode [J] . Florence Geneste, Claude Moinet New Journal of Chemistry . 2004,第6期

机译：共价结合到石墨毡电极上的聚吡啶钌-氧配合物的电催化活性
2. Sensitive single-layered oxygen-sensing systems: Polypyridyl ruthenium(II) complexes covalently attached or deposited as Langmuir-Blodgett monolayer on glass surfaces [J] . Chu BWK, Yam VWW Langmuir: The ACS Journal of Surfaces and Colloids . 2006,第17期

机译：敏感的单层氧气感应系统：聚吡啶钌（II）复合物以Langmuir-Blodgett单层形式共价连接或沉积在玻璃表面上
3. Fabrication of a covalently attached multilayer film electrode containing cobalt phthalocyanine and its electrocatalytic oxidation of hydrazine [J] . Xiaofang Li, Suxia Zhang, Changqing Sun Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2003,第0期

机译：含钴酞菁的共价连接多层膜电极的制备及其对肼的电催化氧化
4. Fabrication of a Covalently Attached Multiplayer Film Electrode ContainingIron Porphyrin and Its Electrochemical Catalysis toward NO2 and H2O2 [C] . Yaqin Fu International seminar on electroanalytical chemistry . 2001

机译：制造共价连接的多人薄膜电极含有铁卟啉及其电化学催化朝向NO2和H2O2
5. I. Symmetrical ligand bridged bimetallic complexes of rhenium(I): Implications for electrocatalytic reduction of carbon dioxide. II. Unimolecular excited state relaxation pathways in polypyridyl complexes of rhenium(I). [D] . Baiano, John Augustus. 1992

机译：I. ligand的对称配体桥联双金属络合物（I）：对电催化还原二氧化碳的影响。二。 poly（I）聚吡啶配合物中的单分子激发态弛豫途径。
6. Axial Coordination Site-Turned Surface ConfinementElectron Transfer and Bio-Electrocatalytic Applications of a HeminComplex on Graphitic Carbon Nanomaterial-Modified Electrodes [O] . Khairunnisa Amreen, Annamalai Senthil Kumar, *, 2018

机译：轴向协调定点旋转表面约束血红素的电子转移和生物电催化应用石墨碳纳米材料修饰电极上的配合物
7. Sensitive Single-Layered Oxygen-Sensing Systems: Polypyridyl Ruthenium(II) Complexes Covalently Attached or Deposited as Langmuir-Blodgett Monolayer on Glass Surfaces [O] . -1

机译：敏感的单层氧传感系统：聚吡啶基钌（II）配合物在玻璃表面上共价附着或沉积为Langmuir-Blodgett单层
8. Electrochemical and Glucose Oxidase Coenzyme Activity of Flavin Adenine Dinucleotide Covalently Attached to Glassy Carbon at the Adenine Amino Group [R] . Miyawaki, O., Wingard, L. B. 1985

机译：腺嘌呤氨基上与玻碳共价连接的黄素腺嘌呤二核苷酸的电化学和葡萄糖氧化酶辅酶活性

Electrocatalytic activity of a polypyridyl ruthenium-oxo complex covalently attached to a graphite felt electrode

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