A photoactive nona-porphyrin with nucleosidic linkers

Nathalie Solladie; Chloe Sooambar; Haiko Herschbach; Jean-Marc Strub; Emmanuelle Leize

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A photoactive nona-porphyrin with nucleosidic linkers

机译：具有核苷接头的光敏九卟啉

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A nona-porphyrin constituted of eight Zn(II) porphyrins anchored to a tetra-nucleosidic free-base porphyrin has been synthesized for its light absorbance capability and its ability to deliver this energy to the central chromophore.In the light harvesting part of the photosynthetic system,solar energy is collected by chlorophylls.The absorption of a photon by a pigment in these antennae is followed by the extremely fast migration of the excited state among the pool of chlorophylls with minimal energy loss until the reaction center is reached.Located within the cell membrane,this center shelters the conversion of solar energy into chemical energy,which in turn is used by the cells to propel protons across the membrane.

机译：已经合成了由八种锌（II）卟啉锚定到四核苷游离碱卟啉构成的九卟啉，因为它具有光吸收能力和将这种能量传递给中心发色团的能力。在光合作用的光收集部分在系统中，通过叶绿素收集太阳能。在这些触角中色素吸收光子后，激发态以极快的速度在叶绿素池中迁移，并且能量损失最小，直到到达反应中心。细胞膜，这个中心阻止了太阳能向化学能的转化，而化学能又被细胞用来推动质子穿过膜。

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《New Journal of Chemistry》 |2005年第12期|共4页
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Nathalie Solladie; Chloe Sooambar; Haiko Herschbach; Jean-Marc Strub; Emmanuelle Leize;
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中图分类化学;
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1. A photoactive nona-porphyrin with nucleosidic linkers [J] . Nathalie Solladie, Chloe Sooambar, Haiko Herschbach, New Journal of Chemistry . 2005,第12期

机译：具有核苷接头的光敏九卟啉
2. Binding of Europium(III) to a Non-Nucleosidic Phenanthroline Linker in DNA [J] . Ching-Hui Huang † Austin Parish † Florent Samain ‡ Florian Garo ‡ Robert Häner ‡ and Janet R. Morrow † American Chemical Society . 2010,第3期

机译：DNA（III）与DNA中非核苷菲咯啉连接子的结合
3. DNA containing non-nucleosidic phenanthrene building blocks with asymmetrical linkers. [J] . Langenegger SM, Malinovskii VL, Wenger D, Nucleosides, nucleotides and nucleic acids . 2007,第8a9期

机译：包含具有非对称接头的非核苷菲结构单元的DNA。
4. Photoactive Compound-Triplex-Forming Oli-gonucleotide Linked Gold Nanoparticle as an Artificial Gene Specific DNA Cleaver Assembly [C] . Tsung-Lin Tsai, Kao-Shu Chuang, Jih-Ru Hwu IEEE Conference on Nanotechnology . 2008

机译：作为人造基因特异性DNA切割机组的光活性化合物 - 三重合核苷酸连接的金纳米粒子
5. Surface Modification of Gold Nanorods for Photoactive Degradation of Fibrin Biopolymer [D] . ?Alshammari, Riyadh Hamdan 2020

机译：纤维蛋白生物聚合物光活性降解金纳米棒的表面改性
6. Combined probes of X-ray scattering and optical spectroscopy reveal how global conformational change is temporally and spatially linked to local structural perturbation in photoactive yellow protein [O] . Tae Wu Kim, Cheolhee Yang, Youngmin Kim, -1

机译：X射线散射和光谱学的组合探针揭示了全局构象变化如何在时间和空间上与光敏黄色蛋白的局部结构扰动相关
7. Study of the Photo-oxidation and Photolysis of Unsaturated and Cross-linked Polyesters (UP) in the Presence of Photoactive or not Inorganic Fillers [O] . Khalil Zahi, Koubaissy Bachar, Akil Mariam 2014

机译：存在光活性或非无机填料的情况下不饱和和交联聚酯（UP）的光氧化和光解的研究
8. Photogeneration of Polymeric Amines: Synthesis and Photocrosslinking of Copolymers Containing Photoactive Carbamate Pendant Groups. [R] . Beecher, J. E., Cameron, J. F., Frechet, J. M. 1992

机译：聚合胺的光生成：含光活性氨基甲酸酯侧基的共聚物的合成和光交联。

A photoactive nona-porphyrin with nucleosidic linkers

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