A catalyst for an acetal hydrolysis reaction from a dynamic combinatorial library

Vial L; Sanders JKM; Otto S

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A catalyst for an acetal hydrolysis reaction from a dynamic combinatorial library

机译：来自动态组合库的乙缩醛水解反应催化剂

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摘要

A transition-state analogue (TSA) for an acetal hydrolysis reaction was found to select and amplify a macrocycle from a dynamic combinatorial library (DCL) of disulfides in water. This host was able to accelerate the reaction by a factor of two; a similar value was progressively reached when the macrocycle was gradually produced in the course of the reaction.

机译：发现用于乙缩醛水解反应的过渡态类似物（TSA）从水中的二硫键动态组合库（DCL）中选择和扩增大环。该宿主能够将反应加速两倍。当在反应过程中逐渐产生大环时，逐渐达到相似的值。

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《New Journal of Chemistry》 |2005年第8期|共3页
作者
Vial L; Sanders JKM; Otto S;
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正文语种 eng
中图分类化学;
关键词
MACROCYCLIC DISULFIDES; SELECTION; GLYCOSIDASE; ANTIBODIES; AMPLIFICATION; CHEMISTRY; EVOLUTION;

机译：大环硫化物;选择;糖苷酶;抗体;扩增;化学;进化;

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1. A catalyst for an acetal hydrolysis reaction from a dynamic combinatorial library [J] . Vial L, Sanders JKM, Otto S New Journal of Chemistry . 2005,第8期

机译：来自动态组合库的乙缩醛水解反应催化剂
2. Efficient in situ three-component formation of chiral oxazoline-Schiff base copper(Ⅱ) complexes: towards combinatorial library of chiral catalysts for asymmetric Henry reaction [J] . Wen Yang, Han Liu, Da-Ming Du Organic & biomolecular chemistry . 2010,第13期

机译：手性恶唑啉-席夫碱铜（Ⅱ）配合物的高效原位三组分形成：针对不对称亨利反应的手性催化剂组合库
3. BEYOND PEPTIDE AND NUCLEIC ACID COMBINATORIAL LIBRARIES-APPLYING UNIONS OF MULTICOMPONENT REACTIONS TOWARDS THE GENERATION OF CARBOHYDRATE COMBINATORIAL LIBRARIES [J] . Goebel M., Ugi I. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第34期

机译：肽和核酸组合文库向碳酸盐组合文库的产生的多元反应联合
4. Combinatorial Approaches for New Catalyst Discovery: The First Homogeneous Catalysts Derived from Combinatorial Technologies for a Variety of Cross-Coupling Reactions [C] . George Y. Li Conference on the Catalysis of Organic Reactions . 2005

机译：新型催化剂的组合方法：第一种衍生自组合技术的均相催化剂，用于各种交叉偶联反应
5. METALLOENZYME MODELS. PART I: NITROGEN ANALOGUES OF CYTOCHROME P-450 MODEL REACTIONS. PART II: ZINC-BASED CATALYSTS FOR PHOSPHATE TRIESTER HYDROLYSIS [D] . GELLMAN, SAMUEL HELMER 1986

机译：金属酶模型。第一部分：细胞色素P-450模型反应的氮类似物。第二部分：磷酸盐三酯水解的锌基催化剂
6. Production of combinatorial libraries of fused genes by sequential transposition reactions [O] . Todd A. Naumann, Igor Y. Goryshin, William S. Reznikoff 2002

机译：通过顺序转座反应产生融合基因的组合文库
7. Base Promotion and Intramolecular Catalysis in Acetal Hydrolysis. Reaction of o-Hydroxybenzaldehyde Diethyl Acetal. [O] . Alpo Kankaanperä, Leena Oinonen, Markku Lahti, 1974

机译：缩醛水解的基础促进和分子内催化。 O-羟基苯甲醛二乙基乙醛的反应。

A catalyst for an acetal hydrolysis reaction from a dynamic combinatorial library

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