The decisive role of oxide content in the formation and crystallization of gallium-lanthanum-sulfide glasses

R.Li; D.Furniss

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The decisive role of oxide content in the formation and crystallization of gallium-lanthanum-sulfide glasses

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A series of gallium-sulfide (GLS) glasses ofdifferent oxide concentration has been made and theirspectroscopic properties, thermal properties, and the crystallizationbehavior of the glasses have been studied. It was revealed that theformability of GLS glasses relies on the existence of a certainamount of oxide content. The thermal stability of GLS glasseschanges as a function of oxide concentration. The results have alsoshown that increasing oxide content caused a shift of the visibleabsorption edge to shorter wavelengths and an increase ofabsorption intensity in the infrared region at the multiphonon edge.Two closely related crystalline phases have been identified in thecrystallized GLS glasses. For the first time it has been revealed thatthermally stable GLS glasses can be made near the eutectic point ofthese two crystal phases by introducing an optimized amount of oxide.

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《Journal of Materials Research》 |1999年第6期|2621-2627|共7页
作者
R.Li; D.Furniss;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类工程材料学;
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The decisive role of oxide content in the formation and crystallization of gallium-lanthanum-sulfide glasses

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