Environmentally friendly Beckmann rearrangement of oximes catalyzed by metaboric acid in ionic liquids

Shu Guo; Youquan Deng

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Environmentally friendly Beckmann rearrangement of oximes catalyzed by metaboric acid in ionic liquids

机译：离子液体中偏硼酸催化的肟的环保贝克曼重排

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摘要

Beckmann rearrangement of several oximes catalyzed by metaboric acid was studied in room temperature ionic liquids.Especially for conversion of cyclohexanone oxime into epsilon-caprolactam,excellent conversion and selectivity were obtained.

机译：在室温离子液体中研究了偏硼酸催化的几种肟的贝克曼重排。特别是环己酮肟向ε-己内酰胺的转化具有良好的转化率和选择性。

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《Catalysis Communications》 |2005年第3期|共4页
作者
Shu Guo; Youquan Deng;
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原文格式 PDF
正文语种 eng
中图分类化学工业;
关键词
Beckmann rearrangement; Oxime; Metaboric acid; Ionic liquid;

机译：贝克曼重排;肟;甲醇;离子液体;

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专利

1. Environmentally friendly Beckmann rearrangement of oximes catalyzed by metaboric acid in ionic liquids [J] . Shu Guo, Youquan Deng Catalysis Communications . 2005,第3期

机译：离子液体中偏硼酸催化的肟的环保贝克曼重排
2. Beckmann rearrangement of oximes catalyzed by cyanuric chloride in ionic liquids [J] . Bettia C, Landini D, Maia A, Synlett . 2008,第6期

机译：氰尿酰氯在离子液体中催化肟的贝克曼重排
3. Clean Beckmann rearrangement of cyclohexanone oxime in caprolactam-based Bronsted acidic ionic liquids [J] . Guo S, Du ZY, Zhang SG, Green chemistry . 2006,第3期

机译：己内酰胺基布朗斯台德酸性离子液体中环己酮肟的清洁贝克曼重排
4. Highly Efficient Oxidation of Toluene to Benzoic Acid Catalyzed by N-Hydroxyphthalimide and Oxime in PEG -1000-based dicationic ionic liquid [C] . Huiling Ding, Lanping Zeng International Conference on Applied Science, Engineering and Technology . 2013

机译：基于PEG -1000基脱硫离子液体的N-羟基邻羟基酰亚胺和肟催化的苯甲苯的高效氧化
5. An environmentally friendly alternative for the conventional acids used in matrix acidizing and acid fracturing of carbonate reservoirs. [D] . Nawik, Adisak. 2017

机译：碳酸盐储层基质酸化和酸裂中使用的常规酸的环保替代品。
6. An Efficient Eco-friendly and Sustainable One-Pot Synthesis of 34-Dihydropyrimidin-2(1H)-ones Directly from Alcohols Catalyzed by Heteropolyanion-Based Ionic Liquids [O] . Renzhong Fu, Yang Yang, Xudong Ma, 2017

机译：杂多阴离子基离子液体直接催化醇合成34-二氢嘧啶-2（1H）-酮的高效环保和可持续的一锅合成
7. Beckmann rearrangement of acetophenone oximes to the corresponding amides organo-catalyzed by trifluoroaceticacid for sustainable NSAIDs synthesis [O] . Giuseppe Quartarone, Elia Rancan, Lucio Ronchin, 2014

机译：苯乙酮肟的贝克曼重排成三氟乙酸有机催化的相应酰胺，从而可持续合成非甾体抗炎药

Environmentally friendly Beckmann rearrangement of oximes catalyzed by metaboric acid in ionic liquids

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