Immobilization of bis(imino)pyridine iron complexes onto mesoporous molecular sieves and their catalytic performance in ethylene oligomerization

Cun-Yue Guo; Hao Xu; Mingge Zhang

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Immobilization of bis(imino)pyridine iron complexes onto mesoporous molecular sieves and their catalytic performance in ethylene oligomerization

机译：双（亚氨基）吡啶铁配合物在介孔分子筛上的固定及其在乙烯低聚反应中的催化性能

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Bis(imino)pyridine iron complexes were supported on MAO-treated mesoporous molecular sieves MCM-41 and SBA-15. The effects of reaction temperature and Al/Fe mole ratio on ethylene oligomerization were investigated in detail. The supported complexes, upon activation with MAO, exhibited good catalytic performance towards ethylene oligomerization and formed linear α-olefins at high reaction temperatures. MCM-41 with relatively narrow pore size tended to produce more lower molar mass α-olefins possibly due to more remarkable confinement effects.

机译：双（亚氨基）吡啶铁络合物负载在MAO处理的介孔分子筛MCM-41和SBA-15上。详细研究了反应温度和Al / Fe摩尔比对乙烯低聚反应的影响。负载的配合物经MAO活化后，对乙烯低聚反应表现出良好的催化性能，并在高反应温度下形成线性α-烯烃。可能由于更显着的限制作用，具有相对窄的孔径的MCM-41倾向于产生更低的摩尔质量的α-烯烃。

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《Catalysis Communications》 |2009年第10期|共5页
作者
Cun-Yue Guo; Hao Xu; Mingge Zhang;
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正文语种 eng
中图分类化学工业;
关键词
Immobilization; Mesoporous molecular sieves; Ethylene; Oligomerization;

机译：固定化;介孔分子筛;乙烯;低聚;

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1. Immobilization of bis(imino)pyridine iron complexes onto mesoporous molecular sieves and their catalytic performance in ethylene oligomerization [J] . Cun-Yue Guo, Hao Xu, Mingge Zhang Catalysis Communications . 2009,第10期

机译：双（亚氨基）吡啶铁配合物在介孔分子筛上的固定及其在乙烯低聚反应中的催化性能
2. Catalytic ethylene oligomerization on cobalt(II) bis(imino)pyridine complexes bearing electron-withdrawing groups [J] . Antonov Artem A., Semikolenova Nina V., Talsi Evgenii P., Journal of Organometallic Chemistry . 2019,第期

机译：催化乙烯低聚钴（II）双（IMINO）吡啶复合物轴承电子 - 抽出基团
3. Ethylene oligomerization using iron complexes: beyond the discovery of bis(imino)pyridine ligands [J] . Adrien Boudier, Pierre-Alain R. Breuil, Lionel Magna, Chemical Communications . 2014,第12期

机译：使用铁络合物进行乙烯低聚：超越双（亚氨基）吡啶配体的发现
4. Spectroscopic characterization and catalytic performances of Iron substituted three dimensional cubic SBA-1 and KIT-5 mesoporous molecular sieves [C] . A. Vinu, G. Chandrasekar, M. Hartmann, International Symposium on Nanoporous Materials; 20050607-10; Niagara Falls(CA) . 2005

机译：铁取代的三维立方SBA-1和KIT-5介孔分子筛的光谱表征和催化性能
5. Reactivity of bis(imino)pyridine cobalt complexes in carbon-hydrogen bond activation and catalytic carbon-carbon and carbon-silicon bond formation. [D] . Atienza, Crisita Carmen Hojilla. 2013

机译：双（亚氨基）吡啶钴配合物在碳氢键活化以及催化碳-碳和碳-硅键形成中的反应性。
6. Bis(imino)pyridine iron complexes for catalytic carbene transfer reactions [O] . Ban Wang, Isaac G. Howard, Jackson W. Pope, 2019

机译：双（亚氨基）吡啶铁配合物用于催化卡宾转移反应
7. Synthesis of a New Polydentate Ligand Obtained by Coupling 2,6-Bis(imino)pyridine and (Imino)pyridine Moieties and Its Use in Ethylene Oligomerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides [O] . -1

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8. Photochemical Formation of Mononuclear Bis and Tris Ethylene Complexes from Irradiation of Iron Pentacarbonyl or Triruthenium Dodecarcarbonyl: Species Involved in Catalytic Alkene Isomerization [R] . Wuu, Y. M., Bentsen, J. G., Brinkley, C. G., 1986

机译：由五羰基铁或三钌十二烷基羰基化合物光化学形成单核双和三乙烯配合物：参与催化烯烃异构化的物种

Immobilization of bis(imino)pyridine iron complexes onto mesoporous molecular sieves and their catalytic performance in ethylene oligomerization

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