Hydride abstraction initiated hydrosilylation of terminal alkenes and alkynes on porous silicon

Schmeltzer JM.; Porter LA.; Stewart MP.; Buriak JM.

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Hydride abstraction initiated hydrosilylation of terminal alkenes and alkynes on porous silicon

机译：氢化物抽象引发了多孔硅上末端烯烃和炔烃的氢化硅烷化

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Hydride abstraction by triphenylcarbenium cations in the presence of terminal alkynes and alkenes results in hydrosilylation at room temperature on hydride-terminated porous silicon surfaces, leading to alkenyl- and alkyl-terminated surfaces, respectively. A wide range of surface terminations are possible as the reaction conditions tolerate a variety of functional groups. Silicon-carbon bond formation is substantiated by Fourier transform infrared and C-13 solid-state NMR spectroscopies, in addition to chemical and stability studies. Generation of an energetic surface silicon-based positive charge is thus a viable route to the formation of silicon-carbon bonds via hydrosilylation, a step previously postulated for the mechanism of exciton-mediated hydrosilylation on photoluminescent nanocrystalline silicon. [References: 47]

机译：在末端炔烃和烯烃的存在下，三苯碳鎓阳离子氢化物的提取导致氢化物封端的多孔硅表面在室温下发生氢化硅烷化，分别导致烯基和烷基封端的表面。由于反应条件可耐受多种官能团，因此可能存在多种表面终止反应。除了化学和稳定性研究以外，傅立叶变换红外光谱和C-13固态NMR光谱证实了硅碳键的形成。因此，基于硅的高能表面正电荷的产生是经由氢化硅烷化形成硅-碳键的可行途径，该步骤先前被假定为在光致发光纳米晶体硅上激子介导的氢化硅烷化机理的步骤。 [参考：47]

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《Langmuir: The ACS Journal of Surfaces and Colloids》 |2002年第8期|共4页
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Schmeltzer JM.; Porter LA.; Stewart MP.; Buriak JM.;
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正文语种 eng
中图分类化学;物理化学（理论化学）、化学物理学;
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1. Hydride abstraction initiated hydrosilylation of terminal alkenes and alkynes on porous silicon [J] . Schmeltzer JM., Porter LA., Stewart MP., Langmuir: The ACS Journal of Surfaces and Colloids . 2002,第8期

机译：氢化物抽象引发了多孔硅上末端烯烃和炔烃的氢化硅烷化
2. Hydrosilylation of Terminal Alkynes Catalyzed by a ONO-Pincer Iridium(III) Hydride Compound: Mechanistic Insights into the Hydrosilylation and Dehydrogenative Silylation Catalysis [J] . Perez-Torrente Jesus J., Duc Hanh Nguyen, Victoria Jimenez M., Organometallics . 2016,第14期

机译：ONO-品位铱（III）氢化物催化的末端炔烃的氢化硅烷化：对氢化硅烷化和脱氢硅烷化催化的机理研究
3. The Catalytic Effect in Opening an Organoactinide Metal Coordination Sphere: Regioselective Dimerization of Terminal Alkynes and Hydrosilylation of Alkynes and Alkenes with PhSiH_3 Promoted by Me_2SiCp''_2Th~nBu_2 [J] . Aswini K. Dash, Ilya Gourevich, Ji Quan Wang, Organometallics . 2001,第24期

机译：打开有机act金属配位球的催化作用：末端炔烃的区域选择性二聚和Me_2SiCp''_ 2Th〜nBu_2促进的PhSiH_3炔烃和烯烃的氢化硅烷化
4. Functionalization of Porous Silicon with Alkenes with Alkynes via Carbocation-Mediated Hydrosilylation [C] . J.M.Schmeltzer, Lon A.Porter, Michael P.Stewart, Materials Research Society Symposium . 2003

机译：用碳粉次介导的氢化硅烷化与炔烃与烯烃的多孔硅的官能化
5. Alkyne hydrosilylation with cationic cyclopentadienylruthenium complexes: Scope, mechanism, and synthetic applications of a metal-catalyzed trans addition process. [D] . Ball, Zachary Thomas. 2005

机译：阳离子环戊二烯基钌配合物的炔烃氢化硅烷化：金属催化的反式加成过程的范围，机理和合成应用。
6. Room Temperature Hydrosilylation of Silicon Nanocrystals with Bifunctional Terminal Alkenes [O] . Yixuan Yu, Colin M. Hessel, Timothy Bogart, -1

机译：用双官能末端烯烃室温度氢化硅纳米晶体
7. Hydrosilylation of terminal alkynes catalyzed by a ONO-pincer iridium(III) hydride compound: Mechanistic insights into the hydrosilylation and dehydrogenative silylation catalysis [O] . Pérez-Torrente, Jesús J., Nguyen, Duc H., Jiménez, M. Victoria, 2017

机译：ONO-钳制氢化铱（III）化合物催化末端炔烃的氢化硅烷化：深入了解氢化硅烷化和脱氢甲硅烷基化催化的机理
8. Procedure Identifying a Polyacetylene Initiator of Olefin Metathesis. The Reactivities of Metal-Carbenes Toward Alkenes and Alkynes [R] . Han, C. C., Katz, T. J. 1985

机译：鉴定烯烃复分解的聚乙炔引发剂的方法。金属 - 卡宾对烯烃和炔烃的反应性

Hydride abstraction initiated hydrosilylation of terminal alkenes and alkynes on porous silicon

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