Vapor phase hydrogenation of furfural to furfuryl alcohol over environmentally friendly Cu-Ca/SiO_2 catalyst

Jing Wu; Yanming Shen; Changhou Liu; Haibin Wang; Caijun Geng

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Vapor phase hydrogenation of furfural to furfuryl alcohol over environmentally friendly Cu-Ca/SiO_2 catalyst

机译：在环保型Cu-Ca / SiO_2催化剂上糠醛的气相加氢为糠醇

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The Cu-Ca/SiO_2 catalysts were prepared by sol-gel and impregnation methods,respectively.A comparative study on their structures has been carried out by XRD,BET,chemisorption of nitrous oxide and XPS techniques.The catalytic performance of two catalysts for vapor phase hydrogenation of furfural to furfuryl alcohol was tested.Compared with the Cu-Ca/SiO_2 catalyst prepared by impregnation method,the Cu-Ca/SiO_2 catalyst prepared by sol-gel technique showed higher copper dispersion and higher activity.In addition,both catalysts revealed high selectivity in hydrogenation of furfural to furfuryl alcohol.

机译：分别采用溶胶-凝胶法和浸渍法制备了Cu-Ca / SiO_2催化剂。通过XRD，BET，一氧化二氮的化学吸附和XPS技术对Cu-Ca / SiO_2催化剂的结构进行了比较研究。两种催化剂对水蒸气的催化性能对糠醛进行氢化为糠醇进行了试验。与浸渍法制备的Cu-Ca / SiO_2催化剂相比，溶胶-凝胶法制备的Cu-Ca / SiO_2催化剂具有较高的铜分散性和活性。在糠醛加氢成糠醇中具有较高的选择性。

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来源
《Catalysis Communications》 |2005年第9期|共5页
作者
Jing Wu; Yanming Shen; Changhou Liu; Haibin Wang; Caijun Geng;
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正文语种 eng
中图分类化学工业;
关键词
Cu-Ca/SiO_2; Furfural; Hydrogenation; Furfuryl alcohol;

机译：Cu-Ca / SiO_2;糠醛;加氢;糠醇;

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1. Vapor phase hydrogenation of furfural to furfuryl alcohol over environmentally friendly Cu-Ca/SiO_2 catalyst [J] . Jing Wu, Yanming Shen, Changhou Liu, Catalysis Communications . 2005,第9期

机译：在环保型Cu-Ca / SiO_2催化剂上糠醛的气相加氢为糠醇
2. Vapour Phase Selective Hydrogenation of Furfural to Furfuryl Alcohol Over Cu-Cr-Zn Mixed Oxide Catalysts Prepared by Utilizing Gamma Radiation [J] . Babu G. Suresh, Rekha V., Francis Sanju, Catalysis Letters . 2019,第10期

机译：通过利用γ辐射制备的Cu-Cr-Zn混合氧化物催化剂的糠醛至糠醇的气相选择性氢化
3. Optimization of ruthenium based catalysts for the aqueous phase hydrogenation of furfural to furfuryl alcohol [J] . Ramirez-Barria Carolina, Isaacs Mark, Wilson Karen, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2018,第期

机译：优化钌催化剂的糠醛水相氢化糠醛至糠醇
4. A Co-promoted Ni-B amorphous nanoalloy catalyst for liquid phase hydrogenation of furfural to furfural alcohol [C] . Changhai DU, Yong ZHAO, De SUN International conference on environmental biotechnology and materials engineering;EBME 2011 . 2011

机译：糠醛液相加氢制糠醇的助催化剂Ni-B非晶态纳米合金催化剂
5. New developments toward the synthesis of heterocycles and applications in green chemistry. I. A simple and essentially one-pot synthesis of N-aminated heterocycles using phase transfer catalyst (Aliquat-336). II. Synthesis of pharmaceutically important pyrrole derivatives. III. Applications in green chemistry: Surfactant-mediated environmentally friendly cleavage of aromatic esters and trans-esterification under solvent-free neutral conditions . [D] . Patel, Nitinchandra. 2005

机译：杂环合成的新进展及其在绿色化学中的应用。 I.使用相转移催化剂（Aliquat-336）简单且基本上一锅合成N-胺化的杂环。二。药学上重要的吡咯衍生物的合成。三，在绿色化学中的应用：在无溶剂的中性条件下，表面活性剂介导的环境友好的芳族酯裂解和酯交换反应。
6. Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water [O] . Xiufang Chen, Ligang Zhang, Bo Zhang, -1

机译：g-C3N4纳米片催化剂在水中负载的Pt纳米颗粒上将糠醛高度选择性氢化为糠醇
7. Gas-Phase Hydrogenation of Furfural to Furfuryl Alcohol over Cu-ZnO-Al2O3 Catalysts Prepared from Layered Double Hydroxides [O] . Guillermo R. Bertolini, Carmen P. Jiménez-Gómez, Juan Antonio Cecilia, 2020

机译：用分层双氢氧化物制备的Cu-ZnO-Al2O3催化剂的糠醛在糠醇中的气相氢化

Vapor phase hydrogenation of furfural to furfuryl alcohol over environmentally friendly Cu-Ca/SiO_2 catalyst

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