Cocatalytic effect of cobalt acetate on aerobic cyclohexene oxidation catalyzed by manganese porphyrin

Yang Li; Xian-Tai Zhou; Hong-Bing Ji

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Cocatalytic effect of cobalt acetate on aerobic cyclohexene oxidation catalyzed by manganese porphyrin

机译：乙酸钴对锰卟啉催化好氧环己烯氧化的共催化作用

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The cocatalytic effect of cobalt acetate on the manganese porphyrin-catalyzed oxidation of cyclohexene by molecular oxygen was investigated. The conversion of cyclohexene and the selectivity toward epoxide were significantly improved, whereas the formation of 2-cyclohexen-ol was restricted in the presence of the cocatalyst. A cocatalytic mechanism involving cobalt oxide ([Co-O2]~+) as the active species for enhancing cyclohexene activity and selectivity toward epoxide was proposed.

机译：研究了乙酸钴对锰卟啉催化的分子氧氧化环己烯的共催化作用。环己烯的转化率和对环氧化物的选择性显着提高，而2-环己烯醇的形成在助催化剂存在下受到限制。提出了以氧化钴（[Co-O2]〜+）为活性物种的共催化机理，以提高环己烯的活性和对环氧化物的选择性。

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《Catalysis Communications》 |2012年第null期|共5页
作者
Yang Li; Xian-Tai Zhou; Hong-Bing Ji;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Biomimetic oxidation; Metalloporphyrin; Cyclohexene oxidation; Cocatalyst;

机译：仿生氧化;金属卟啉;环己烯氧化;助催化剂;

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专利

1. Cocatalytic effect of cobalt acetate on aerobic cyclohexene oxidation catalyzed by manganese porphyrin [J] . Yang Li, Xian-Tai Zhou, Hong-Bing Ji Catalysis Communications . 2012,第Null期

机译：乙酸钴对锰卟啉催化好氧环己烯氧化的共催化作用
2. Aerobic oxidation of cyclohexene catalyzed by Fe(III)(5,10,15,20-tetrakis(pentafluorophenyl)porphyrin)Cl in supercritical CO_2 [J] . Yoshiaki Kokubo, Xiao-Wen Wu, Yoshito Oshima, The Journal of Supercritical Fluids . 2004,第2期

机译：Fe（III）（5,10,15,20-四（五氟苯基）卟啉）Cl在超临界CO_2中的有氧氧化环己烯
3. Cyclohexene Promoted Efficient Biomimetic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Manganese Porphyrin under Mild Conditions [J] . Xiao-Hui Liu, Hai-Yang Yu, Can Xue, 中国化学（英文版） . 2020,第005期

机译：环己烯促进了在温和条件下通过锰卟啉催化的羰基化合物的有效仿生氧化醇
4. Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Bifunctional Aluminum Porphyrin Complexes [C] . Chihiro Maeda, Hideki Tokuda, Tadashi Ema 日本化学会春季年会講演予稿集 . 2018

机译：双官能铝卟啉配合物催化环己烯和二氧化碳的共聚合
5. Supramolecular effects in manganese(III) porphyrin-catalyzed epoxidation reactions. [D] . Merlau, Melissa Lee. 2001

机译：锰（III）卟啉催化的环氧化反应中的超分子效应。
6. Alternating copolymerization of carbon dioxide and cyclohexene oxide catalyzed by salen CoIII(acetate) complexes [O] . Yongsheng Niu, Hongchun Li -1

机译：Salen CoIII（乙酸盐）配合物催化的二氧化碳和环己烯氧化物的交替共聚
7. The Effect of Benzylviologen on Manganese Porphyrin-catalyzed Epoxidation Reaction of Cyclohexene [O] . 鈴木, 良弘, 高橋, 光信, 松井, 修一, 1992

机译：苄基紫杉醇对锰卟啉催化环己烯环氧化反应的影响
8. Epoxidation of Styrene with Aqueous Hypochlorite Catalyzed by a Manganese (III)Porphyrin Bound to Colloidal Anion-Exchange Particles [R] . Turk, H., Ford, W. T. 1991

机译：锰（III）卟啉催化苯乙烯与次氯酸盐的环氧化反应与胶体阴离子交换颗粒结合

Cocatalytic effect of cobalt acetate on aerobic cyclohexene oxidation catalyzed by manganese porphyrin

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