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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Silylene-assisted hydride transfer to CO2 and CS2 at a P2SiRu pincer-type complex
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Silylene-assisted hydride transfer to CO2 and CS2 at a P2SiRu pincer-type complex

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摘要

The synthesis and characterization of base-stabilized and base-free pincer-type bis(phosphine)/silylene P2SiRu complexes are reported. The base-free complex readily reduces CO2 and CS2 via silylene-assisted hydride transfer, affording structurally distinct products with silicon-to-ruthenium formate and dithioformate bridges.

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