Mild and efficient oxidation of 2-pyrazolines and isoxazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane-NH4Cl-HOAc in water-MeCN

Khosravi Kaveh

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Mild and efficient oxidation of 2-pyrazolines and isoxazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane-NH4Cl-HOAc in water-MeCN

机译：在水-MeCN中通过反式3,5-二氢过氧-3,5-二甲基-1,2-二氧杂戊环-NH4Cl-HOAc轻度而有效地氧化2-吡唑啉和异恶唑啉

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An efficient method has been developed for oxidative aromatization of 2-pyrazolines and isoxazolines into their corresponding 2-pyrazoles and isoxazoles under mild conditions. In this method, trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane-NH4Cl-HOAc was used as a novel and effective oxidant in water-MeCN at room temperature with good yields.

机译：已经开发出一种在温和条件下将2-吡唑啉和异恶唑啉氧化芳香化为它们相应的2-吡唑和异恶唑的有效方法。在这种方法中，反式-3,5-二氢过氧-3,5-二甲基-1，2-二氧杂戊环-NH4Cl-HOAc在室温下作为新型有效的氧化剂在水-MeCN中使用。

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来源
《Research on Chemical Intermediates》 |2015年第8期|共8页
作者
Khosravi Kaveh;
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正文语种 eng
中图分类有机化学;
关键词
trans-3; 5-Dihydroperoxy-3; 5-dimethyl-1; 2-dioxalane; 2-Pyrazolines; Isoxazolines; Pyrazoles; Isoxazoles; Ammonium chloride;

机译：反式-3;5-二氢过氧-3;5-二甲基-1;2-二氧杂戊烷;2-吡唑啉;异恶唑啉;吡唑;异恶唑;氯化铵;

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1. Mild and efficient oxidation of 2-pyrazolines and isoxazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane-NH4Cl-HOAc in water-MeCN [J] . Khosravi Kaveh Research on Chemical Intermediates . 2015,第8期

机译：在水-MeCN中通过反式3,5-二氢过氧-3,5-二甲基-1,2-二氧杂戊环-NH4Cl-HOAc轻度而有效地氧化2-吡唑啉和异恶唑啉
2. Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane/HOAc/KI system as a new and mild catalyst for efficient synthesis of 1H-benzimidazoles and 1H-benzothiazoles in water [J] . Kaveh Khosravi, Akbar Mobinikhaledi, Samira Kazemi, Iranian Journal of Catalysis . 2014,第1期

机译：反式-3,5-二氢过氧-3,5-二甲基-1,2-二氧戊环/ HOAc / KI体系是一种新型温和催化剂，可在水中高效合成1H-苯并咪唑和1H-苯并噻唑
3. Green, mild and efficient bromination of aromatic compounds by HBr promoted by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane in water as a solvent [J] . Kaveh Khosravi, Samira Kazemi 中国化学快报（英文版） . 2012,第004期

机译：反式-3,5-二氢过氧-3,5-二甲基-1,2-二氧戊环促进了HBr对芳族化合物的绿色，温和和有效溴化反应
4. Strongly Coupled Metal/Oxide Heterointerface for Efficient Ammonia Electrosynthesis at Mild Condition [C] . Bin Hua, Meng Li, Dong Ding Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：强烈偶联的金属/氧化物异化器，用于在温和条件下有效氨电耦合
5. Eco-Friendly Cavity-Containing Iron Oxides Prepared by Mild Routes as Very Efficient Catalysts for the Total Oxidation of VOCs [O] . Rut Sanchis, Daniel Alonso-Domínguez, Ana Dejoz, 2018

机译：通过轻度路线制备的生态友好型腔体氧化铁是非常有效的VOCs完全氧化催化剂
6. Mild and efficient oxidation of 2-pyrazolines and isoxazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane–NH4Cl–HOAc in water–MeCN [O] . Kaveh Khosravi 2014

机译：在水-MeCN中通过反式-3,5-二氢过氧-3,5-二甲基-1,2-二氧杂戊烷-NH4Cl-HOAc轻度而有效地氧化2-吡唑啉和异恶唑啉

Mild and efficient oxidation of 2-pyrazolines and isoxazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane-NH4Cl-HOAc in water-MeCN

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