Copper-catalyzed cyanoalkylarylation of activated alkenes with AIBN: a convenient and efficient approach to cyano-containing oxindoles

Wei Wei; Wen Jiangwei; Yang Daoshan; Guo Mengyuan; Tian Laijin; You Jinmao; Wang Hua

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Copper-catalyzed cyanoalkylarylation of activated alkenes with AIBN: a convenient and efficient approach to cyano-containing oxindoles

机译：AIBN的铜催化活化烯烃的氰基烷基芳基化：一种方便高效的含氰基吲哚的方法

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A novel, simple, and cost-effective copper-catalyzed direct cyanoalkylarylation of activated alkenes with AIBN has been developed with cheap K2S2O8 as the oxidant. A series of cyano-containing oxindoles that are otherwise difficult to obtain through previous methods were efficiently synthesized using this protocol.

机译：用廉价的K2S2O8作为氧化剂，开发了一种新颖，简单且经济高效的铜催化的活性烯烃与AIBN的直接氰基烷基芳基化反应。使用该协议可以有效地合成一系列难以通过以前的方法获得的含氰基羟吲哚。

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《RSC Advances》 |2014年第89期|共4页
作者
Wei Wei; Wen Jiangwei; Yang Daoshan; Guo Mengyuan; Tian Laijin; You Jinmao; Wang Hua;
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正文语种 eng
中图分类化学;
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1. Copper-catalyzed cyanoalkylarylation of activated alkenes with AIBN: a convenient and efficient approach to cyano-containing oxindoles [J] . Wei Wei, Wen Jiangwei, Yang Daoshan, RSC Advances . 2014,第89期

机译：AIBN的铜催化活化烯烃的氰基烷基芳基化：一种方便高效的含氰基吲哚的方法
2. Copper-Catalysed Alkylarylation of Activated Alkenes Using AIBN and Beyond: An Access to Cyano-Containing Oxindoles [J] . Zhou Dong, Li Zi-Hao, Li Jie, European journal of organic chemistry . 2015,第7期

机译：使用AIBN及其以后的铜催化活性烯烃的烷基芳基化反应：获得含氰基吲哚的方法
3. Iron- or copper-catalyzed cascade chloromethylation of activated alkenes: Efficient access to chlorinated oxindoles [J] . Li Dengke, Shen Xianfu Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2020,第37期

机译：铁 - 或铜催化的级联活化烯烃的氯甲基化：有效进入氯化氧吲哚
4. AN EFFICIENT COMPUTATIONAL INVERSE APPROACH FOR OPTIMAL DESIGN OF LOCALIZED ACTIVATION AND ACTUATION FOR MORPHING SMP STRUCTURES [C] . Shuang Wang, John C. Brigham ASME conference on smart materials, adaptive structures and intelligent systems . 2013

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5. Development of Novel Alkene Oxindole Derivatives AsOrally Efficacious AMP-Activated Protein Kinase Activators [O] . Li-Fang Yu, †, Yuan-Yuan Li, 2013

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6. Copper-catalyzed alkyrarylation of activated alkenes using isocyanides as the alkyl sources: An efficient radical access to 3,3-dialkylated oxindoles [O] . Zhao Yaping, Li Zhenghua, Sharma Upendra Kumar, 2016

机译：铜催化的使用异氰酸酯作为烷基源的活化烯烃的烷基芳基化：有效地自由基反应制取3,3-二烷基化的吲哚

Copper-catalyzed cyanoalkylarylation of activated alkenes with AIBN: a convenient and efficient approach to cyano-containing oxindoles

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