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Electrochromic response of pulsed laser deposition prepared WO3-TiO2 composite film

机译:脉冲激光沉积制备的WO3-TiO2复合薄膜的电致变色响应

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摘要

Electrochromic films of WO3 with varying content of TiO2, as a composite, were prepared via pulsed laser deposition method. The composite films exhibited cathodic electrochromism, which changed the original colorless appearance to a deep blue color. The films were examined for their structure, morphology, ultraviolet to visible photon absorption and chromic changes in electric fields. Pure WO3 film showed stronger absorption at 600-800 nm wavelength of light than the composite films, which corresponds to blue color. The most intensive absorption wavelength of light could be modulated with TiO2 inclusion, leading to a respective color change from dark blue to gem blue of the as-deposited WO3-TiO2-ITO glass. This work may serve as a basis for electrochromic windows and display device applications.
机译:通过脉冲激光沉积法制备了不同含量的TiO2的WO3电致变色薄膜。复合膜表现出阴极电致变色,其将原来的无色外观变为深蓝色。检查了薄膜的结构,形态,紫外到可见光子的吸收以及电场中铬的变化。纯WO3膜在600-800 nm波长的光下显示出比复合膜强的吸收率,这对应于蓝色。可以用TiO2夹杂物来调制最强的光吸收波长,从而导致所沉积的WO3-TiO2-ITO玻璃的颜色从深蓝色变为宝石蓝。这项工作可以作为电致变色窗和显示设备应用的基础。

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