A Pd complex of a NNN pincer ligand supported on gamma-Fe2O3@SiO2 as the first magnetically recoverable heterogeneous catalyst for C-P bond forming reactions

Sobhani Sara; Vahidi Zahra; Zeraatkar Zohre; Khodadadi Samaneh

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A Pd complex of a NNN pincer ligand supported on gamma-Fe2O3@SiO2 as the first magnetically recoverable heterogeneous catalyst for C-P bond forming reactions

机译：NNN钳形配体的Pd络合物负载在γ-Fe2O3@ SiO2上，是第一个进行C-P键形成反应的磁性可回收非均相催化剂

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A Pd complex of a NNN pincer ligand supported on gamma-Fe2O3@SiO2 as a new phosphine-free Pd catalyst was synthesized and characterized by different methods such as SEM, TEM, FT-IR, TGA, ICP, XRD, XPS and elemental analysis. The synthesized catalyst was successfully used as the first magnetically recoverable heterogeneous catalyst for the synthesis of arylphosphonates via C-P bond formation by a crosscoupling reaction of different electrophilic benzenes with phosphite esters under solvent-free conditions.

机译：合成了一种新型的无膦Pd催化剂，负载在γ-Fe2O3@ SiO2上的NNN钳形配体的Pd配合物，并通过SEM，TEM，FT-IR，TGA，ICP，XRD，XPS和元素分析等方法进行了表征。合成的催化剂成功地用作第一种可通过磁性回收的非均相催化剂，用于在无溶剂条件下通过不同亲电子苯与亚磷酸酯的交联反应，通过C-P键形成合成芳基膦酸酯。

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《RSC Advances》 |2015年第46期|共8页
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Sobhani Sara; Vahidi Zahra; Zeraatkar Zohre; Khodadadi Samaneh;
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中图分类化学;
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1. A Pd complex of a NNN pincer ligand supported on gamma-Fe2O3@SiO2 as the first magnetically recoverable heterogeneous catalyst for C-P bond forming reactions [J] . Sobhani Sara, Vahidi Zahra, Zeraatkar Zohre, RSC Advances . 2015,第46期

机译：NNN钳形配体的Pd络合物负载在γ-Fe2O3@ SiO2上，是第一个进行C-P键形成反应的磁性可回收非均相催化剂
2. Pd complex of an NNN pincer ligand supported on gamma-Fe2O3@SiO2 magnetic nanoparticles: a new catalyst for Heck, Suzuki and Sonogashira coupling reactions [J] . Sobhani Sara, Zeraatkar Zohre, Zarifi Farzaneh New Journal of Chemistry . 2015,第9期

机译：γ-Fe2O3@ SiO2磁性纳米粒子上负载的NNN钳形配体的Pd配合物：Heck，Suzuki和Sonogashira偶联反应的新催化剂
3. Stabilization of Au NPs on symmetrical tridentate NNN-Pincer ligand grafted on magnetic support as water dispersible and recyclable catalyst for coupling reaction of terminal alkyne [J] . Nasrin Zohreh, Seyed Hassan Hosseini, Mahboobeh Jahani, Journal of Catalysis . 2017,第期

机译：对称三齿的Au nps稳定化 nnn -pincer配体接枝在磁性载体上作为水分散和可回收催化剂，用于炔烃偶联反应的偶联反应
4. Preparation of Transition Metal Complexes Based on NNN-Type Pincer Ligand Incorporating Imidazo1,5-apyridine Moiety and Their Photofunctionality [C] . Fumitoshi Yagishita, Shun Ikami, Souta Shimokawa 日本化学会春季年会講演予稿集 . 2018

机译：基于NNN型钳子配体的过渡金属配合物的制备掺入咪唑1,5-A吡啶部分及其光功能性
5. Pincer complexes of diamido-pyridine based ligand as catalysts for C-Cl and C-H bond activation for cross-coupling reactions. [D] . Gartia, Yashraj. 2013

机译：基于二酰胺基-吡啶基配体的钳形配合物，可作为C-Cl和C-H键活化的催化剂进行交叉偶联反应。
6. Cellulose-supported chiral rhodium nanoparticles as sustainable heterogeneous catalysts for asymmetric carbon–carbon bond-forming reactions [O] . Tomohiro Yasukawa, Hiroyuki Miyamura, Shū Kobayashi 2015

机译：纤维素负载的手性铑纳米粒子可作为非均相碳-碳键形成反应的可持续多相催化剂
7. Correction: Pd complex of an NNN pincer ligand supported on γ-Fe2O3@SiO2 magnetic nanoparticles: a new catalyst for Heck, Suzuki and Sonogashira coupling reactions [O] . Sara Sobhani, Zohre Zeraatkar, Farzaneh Zarifi 2016

机译：校正：NNN钳子配体的PD络合物，支持γ-Fe2O3 @ SiO2磁性纳米粒子：一种新的Heck，Suzuki和Sonogashira偶联反应的新催化剂
8. Application of Trianionic Pincer Ligands to Reactions Involving Group VI Alkylidynes, Metal-Metal Multiple Bonds, and Group IV Amides; Master's thesis [R] . Peloquin, A. J. 2008

机译：Trianionic pincer配体在涉及VI族烷基二炔，金属 - 金属多键和IV族酰胺的反应中的应用;硕士论文

A Pd complex of a NNN pincer ligand supported on gamma-Fe2O3@SiO2 as the first magnetically recoverable heterogeneous catalyst for C-P bond forming reactions

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