• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Multifunctional Zn(II)/Cd(II) metal complexes for tunable luminescence properties and highly efficient dye-sensitized solar cells
【24h】

Multifunctional Zn(II)/Cd(II) metal complexes for tunable luminescence properties and highly efficient dye-sensitized solar cells

机译：具有可调发光性能的多功能Zn（II）/ Cd（II）金属配合物和高效染料敏化太阳能电池

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

We design two novel d(10) metal complexes [Zn(3-qlc)(2)](n) (Zn1), [Cd(3-qlc)(2)](n) (Cd1) (3-Hqlc = quinoline-3-carboxylic acid), which display similar 2D layer structures, and further form 3D 6-connected primitive cubic (pcu) network topology via pi center dot center dot center dot pi stacking interactions with the point symbol {4(12).6(3)}. Complexes Zn1 and Cd1 exhibit tunable luminescence and photovoltaic properties as a new type of multifunctional materials. Zn1 and Cd1 show tunable luminescence from blue to green by varying the temperature in the solid state. What's more, both of them exhibit excellent aggregation-induced emission (AIE) properties in DMSO/water mixtures. Encouraged by the UV-visible absorption in an ethanol solution result, Zn1 and Cd1 can be considered as co-sensitizers in combination with N719 to investigate their effect on enhancing the dye-sensitized solar cells (DSSCs) performance. Zn1 and Cd1 could overcome the deficiency in the ruthenium complex N719 absorption in the ultraviolet and blue-violet region, offsetting competitive visible light absorption of I-3(-) and reducing the charge recombination of injected electrons. After being co-sensitized with Zn1 and Cd1, the devices co-sensitized by Zn1/N719 and Cd1/N719 yield an overall efficiency of 7.75% and 7.70%, which are 44.59% and 43.66% higher than that of the device sensitized only by N719 (5.36%).
机译：我们设计了两种新颖的d（10）金属配合物[Zn（3-qlc）（2）]（n）（Zn1），[Cd（3-qlc）（2）]（n）（Cd1）（3-Hqlc =喹啉3-羧酸），它们显示相似的2D层结构，并通过与点符号{4（12）的pi中心点中心点中心点pi堆叠相互作用进一步形成3D 6连接的原始立方（pcu）网络拓扑。 6（3）}。配合物Zn1和Cd1作为新型多功能材料具有可调节的发光和光伏特性。 Zn1和Cd1通过改变固态温度显示从蓝色到绿色的可调发光。而且，它们在DMSO /水混合物中均表现出出色的聚集诱导发射（AIE）特性。受乙醇溶液中UV-可见光吸收的鼓舞，可以将Zn1和Cd1与N719一起用作共敏化剂，以研究它们对增强染料敏化太阳能电池（DSSC）性能的影响。 Zn1和Cd1可以克服钌络合物N719在紫外和蓝紫色区域吸收的不足，从而抵消I-3（-）的竞争性可见光吸收，并减少注入电子的电荷重组。与Zn1 / Cd1共敏后，由Zn1 / N719和Cd1 / N719共敏的器件产生的总效率为7.75％和7.70％，比仅由Zn1和Cd1敏化的器件的总效率分别高44.59％和43.66％。 N719（5.36％）。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号