• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Effective heterogeneous electro-Fenton process of m-cresol with iron loaded actived carbon
【24h】

Effective heterogeneous electro-Fenton process of m-cresol with iron loaded actived carbon

机译：铁负载活性炭对间甲酚的有效异质电-芬顿过程

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The degradation of m-cresol (MC) has been investigated by a heterogeneous electro-Fenton process using iron loaded activated carbon (Fe-AC) as the heterogeneous electro-Fenton catalyst. Experimental results demonstrated that MC was effectively removed through an electro-Fenton process. Calculated TOC removal and overall energy consumption showed that the use of a low iron concentration (28 mg L-1) increases the efficiency of the process. The reactions followed a pseudo-first order kinetic equation and kinetic coefficients confirm that the MC reduction, when it is alone, is faster than in the presence of a similar compound, tert-butylhydroquinone (TBHQ) (from 0.0935 to 0.0692 min(-1)); therefore TBHQ exerts an antioxidative protection effect. In all cases, it is concluded that heterogeneous electro-Fenton treatment with Fe-AC follows a two-step process: adsorption and oxidation; allowing removal rates higher than in the literature. In addition, the reusability of this catalyst was demonstrated by operating it in continuous mode. Finally, LC-MS analysis allowed the development of a plausible degradation route.
机译：间苯甲酚（MC）的降解已通过非均相电Fenton工艺进行了研究，该方法使用铁负载活性炭（Fe-AC）作为非均质电Fenton催化剂。实验结果表明，MC是通过电子芬顿工艺有效去除的。计算出的总有机碳去除量和总能耗表明，使用低铁浓度（28 mg L-1）可以提高工艺效率。反应遵循拟一阶动力学方程式，动力学系数证实，单独存在时，MC还原比在类似化合物叔丁基对苯二酚（TBHQ）的存在下更快（从0.0935到0.0692 min（-1 ））;因此，TBHQ具有抗氧化保护作用。在所有情况下，得出的结论是，用Fe-AC进行异质电芬顿处理遵循两步过程：吸附和氧化;吸附和氧化。允许去除率比文献中更高。另外，通过以连续模式操作证明了该催化剂的可重复使用性。最后，LC-MS分析允许开发合理的降解途径。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号