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Inhibition of copper corrosion in cooling seawater under flowing conditions by novel pyrophosphate

机译:新型焦磷酸盐在流动条件下抑制冷却海水中铜的腐蚀

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The inhibition of copper corrosion in cooling seawater by novel pyrophosphate SrNiP2O7 (SNP) was investigated under flowing conditions using mass-loss and electrochemical methods. The surface morphology was characterized by SEM coupled with EDX spectra. Comparable results show that SNP acts as a mixed-type inhibitor with predominantly cathodic effectiveness, suppressing the corrosive process by physical adsorption on the copper surface. The highest inhibition efficiency obtained from mass-loss, polarization and EIS measurements are 92.7%, 94.8% and 97.1%, respectively, at 120 mg L-1 of SNP. The influence of increasing temperature on SNP inhibitor efficiency has been studied, and the activation energy has been calculated. Surface morphology observations evidenced the formation of a protective SNP film over the metal surface.
机译:采用质量损失和电化学方法研究了新型焦磷酸盐SrNiP2O7(SNP)在冷却海水中对铜腐蚀的抑制作用。通过SEM结合EDX光谱表征表面形态。可比较的结果表明,SNP作为混合型抑制剂具有主要的阴极效力,可通过物理吸附在铜表面上来抑制腐蚀过程。在120 mg L-1的SNP下,通过质量损失,极化和EIS测量获得的最高抑制效率分别为92.7%,94.8%和97.1%。研究了温度升高对SNP抑制剂效率的影响,并计算了活化能。表面形态学观察证明在金属表面上形成了保护性SNP膜。

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