Highly efficient carbon catalyzed aerobic selective oxidation of benzylic and allylic alcohols under transition-metal and heteroatom free conditions

Yang Huimin; Cui Xinjiang; Deng Youquan; Shi Feng

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Highly efficient carbon catalyzed aerobic selective oxidation of benzylic and allylic alcohols under transition-metal and heteroatom free conditions

机译：在无过渡金属和无杂原子的条件下高效碳催化的苄基和烯丙基醇的有氧选择性氧化

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The aerobic oxidation of benzylic and allylic alcohols has been realized with carbon material as the catalyst in the absence of transition-metal and heteroatoms. Under the optimized reaction conditions, aldehyde and acid can be selectively synthesized with up to 99% yields. The carbon catalyst can be easily recovered from the reaction mixture and can be reused for 5 runs without deactivation.

机译：在没有过渡金属和杂原子的情况下，用碳材料作为催化剂已经实现了苄基和烯丙基醇的好氧氧化。在优化的反应条件下，可以高达99％的产率选择性合成醛和酸。可以容易地从反应混合物中回收碳催化剂，并且可以在不失活的情况下重复使用5次。

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《RSC Advances》 |2014年第104期|共5页
作者
Yang Huimin; Cui Xinjiang; Deng Youquan; Shi Feng;
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1. Highly efficient carbon catalyzed aerobic selective oxidation of benzylic and allylic alcohols under transition-metal and heteroatom free conditions [J] . Yang Huimin, Cui Xinjiang, Deng Youquan, RSC Advances . 2014,第104期

机译：在无过渡金属和无杂原子的条件下高效碳催化的苄基和烯丙基醇的有氧选择性氧化
2. Solid supported Ru(0) nanopartides: an efficient ligand-free heterogeneous catalyst for aerobic oxidation of benzylic and allylic alcohol to carbonyl [J] . Pralay Das, Nidhi Aggarwal, Nitul Ranjan Guha Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2013,第23期

机译：固体负载Ru（0）纳米粒子：有效的无配体非均相催化剂，用于将苄基和烯丙醇好氧氧化为羰基
3. Efficient and selective palladium-catalyzed direct oxidative esterification of benzylic alcohols under aerobic conditions [J] . Yongke Hu, Bindong Li Tetrahedron . 2017,第52期

机译：有氧条件下有效和选择性钯催化的苄醇的直接氧化酯化
4. Aerobic Oxidation of Benzylic Alcohols Catalyzed by Palladium-Bisoxazoline Monolayer on Single Crystal Silicon Surface [C] . Kenji Hara, Shinobu Tayama, Hidekazu Kano, Symposium on Organometallic Chemistry . 2004

机译：钯 - 双恶唑啉单层催化在单晶硅表面上催化的有氧氧化
5. Palladium-catalyzed oxidations of alcohols and olefins under aerobic conditions [D] . Schultz, Mitchell John 2006

机译：有氧条件下钯催化的醇和烯烃的氧化
6. Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition [O] . Cong Ye, Yanbin Zhang, Aishun Ding, -1

机译：有氧条件下可见光敏化剂催化的高选择性光氧化从硫醚转化为亚砜
7. Selective Oxidation of Benzylic and Allylic Alcohols Using Strontium Manganate in the Presence of Lewis Acids in Solution and under Solvent-Free Conditions [O] . 2004

机译：在溶液和无溶剂条件下使用锰酸盐的锶甘露出锶的选择性氧化

Highly efficient carbon catalyzed aerobic selective oxidation of benzylic and allylic alcohols under transition-metal and heteroatom free conditions

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