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Levulinic acid production from Cicer arietinum, cotton, Pinus radiata and sugarcane bagasse

机译:姬松茸,棉花,辐射松和甘蔗渣生产的白蛋白

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摘要

Levulinic acid is a key platform chemical. Even gasoline range chemicals could be produced from levulinic acid making it a strategically significant compound. Producing levulinic acid from biomass is attractive from economic as well as environmental aspects. An acid catalyzed hydrothermal process for converting biomass to levulinic acid is reported. The effect of biomass type, acid (HCl) concentration, and reaction temperature of hydrothermal treatment on the conversion of biomass and yield of levulinic acid were studied. Widely available cellulosic biomass and agricultural wastes, namely, Cicer arietinum, cotton, Pinus radiata and sugarcane bagasse were successfully converted to levulinic acid. Although HPCL analysis could not be performed, qualitative and quantitative analysis of levulinic acid was conducted using C-13 and H-1 NMR spectroscopy. Under optimal reaction conditions (423 K, 1 M HCl, 2 h) the yields of levulinic acid obtained from Cicer arietinum, cotton, Pinus radiata and sugarcane bagasse were 32.6, 44.0, 19.0 and 36.5 wt%.
机译:乙酰丙酸是关键的平台化学品。乙酰丙酸甚至可以生产汽油范围的化学品,使其成为具有战略意义的化合物。从生物质生产乙酰丙酸在经济以及环境方面都是有吸引力的。报道了将生物质转化为乙酰丙酸的酸催化水热过程。研究了生物质类型,酸(HCl)浓度和水热处理反应温度对生物质转化率和乙酰丙酸产率的影响。广泛使用的纤维素类生物质和农业废料,即阿里奇,棉花,辐射松和甘蔗渣已成功转化为乙酰丙酸。尽管无法进行HPCL分析,但是使用C-13和H-1 NMR光谱对乙酰丙酸进行了定性和定量分析。在最佳反应条件(423 K,1 M HCl,2 h)下,得自于苹果,棉花,辐射松和甘蔗渣的乙酰丙酸的收率为32.6、44.0、19.0和36.5 wt%。

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