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Towards the understanding of the effect of oxygen on the electrocatalytic activity of microbial biofilms: a spectroelectrochemical study

机译:理解氧对微生物生物膜的电催化活性的影响:光谱电化学研究

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摘要

Under anoxic conditions, microbial biofilms of metal-respiring bacteria grown on electrodes oxidize an organic substrate and generate electrocatalytic currents. Exposing the biofilm to molecular oxygen suppresses the electrocatalytic current completely. Chronoamperometry and resonance Raman scattering performed simultaneously on the same mixed culture biofilm show that current suppression is caused by the rapid oxygen-induced oxidation of the outer membrane cytochromes wiring the cell metabolism to the electrode.
机译:在缺氧条件下,生长在电极上的金属呼吸细菌的微生物生物膜会氧化有机基质并产生电催化电流。将生物膜暴露于分子氧会完全抑制电催化电流。在同一混合培养生物膜上同时进行的计时安培法和共振拉曼散射表明,电流抑制是由氧气引起的外膜细胞色素的快速氧化引起的,该氧化作用将细胞的新陈代谢连接到电极上。

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