Copper promoted radical addition/cyclization of azobisisobutyronitrile with arylacrylamides: a convenient process to synthesize 3-(2 '-cyano alkyl) oxindoles

Wang Ruihong; Bao Weiliang

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Copper promoted radical addition/cyclization of azobisisobutyronitrile with arylacrylamides: a convenient process to synthesize 3-(2 '-cyano alkyl) oxindoles

机译：铜促进偶氮二异丁腈与芳基丙烯酰胺的自由基加成/环化：合成3-（2'-氰基烷基）吲哚的简便方法

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摘要

A CuI promoted radical addition/cyclization of azobisisobutyronitrile with alkenes was developed. The reaction provided a facile pathway for synthesis of 3-(2'-cyano alkyl) oxindoles. The cyano group is versatile for facile conversion into a diverse class of functionalities.

机译：开发了CuI促进偶氮二异丁腈与烯烃的自由基加成/环化反应。该反应提供了用于合成3-（2'-氰基烷基）羟吲哚的简便途径。氰基基团具有多种功能，可轻松转换为多种功能。

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《RSC Advances》 |2015年第71期|共3页
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Wang Ruihong; Bao Weiliang;
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正文语种 eng
中图分类化学;
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1. Copper promoted radical addition/cyclization of azobisisobutyronitrile with arylacrylamides: a convenient process to synthesize 3-(2 '-cyano alkyl) oxindoles [J] . Wang Ruihong, Bao Weiliang RSC Advances . 2015,第71期

机译：铜促进偶氮二异丁腈与芳基丙烯酰胺的自由基加成/环化：合成3-（2'-氰基烷基）吲哚的简便方法
2. Iron(III) acetylacetonate catalyzed tandem oxidative addition/cyclization of simple amides with alkenes: a convenient process to synthesize 3-amido oxindoles [J] . Wang Ruihong, Bao Weiliang Tetrahedron . 2015,第38期

机译：乙酰丙酮铁（III）催化简单酰胺与烯烃的串联氧化加成/环化：合成3-酰胺基吲哚的简便方法
3. A metal-free synthesis of oxindoles by a radical addition-cyclization onto N-arylacrylamides with xanthates [J] . Wang Shucheng, Huang Xuhu, Li Bowen, Tetrahedron . 2015,第12期

机译：通过黄原酸酯在N-芳基丙烯酰胺上的自由基加成环化反应实现金属吲哚的无金属合成
4. 'Greening' of Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions [C] . Tomislav Pintauer ACS symposium on controlled/living radical polymerization . 2009

机译：铜催化原子的“绿化”转移自由基添加（ATRA）和环化（ATRC）反应
5. Ascorbic Acid-Initiated Tandem Radical Cyclization of N-Arylacrylamides to Give 33-Disubstituted Oxindoles [O] . Sheng Liu, Pi Cheng, Wei Liu, 2015

机译：N-芳基丙烯酰胺抗坏血酸引发的串联自由基环化反应得到33-二取代的羟吲哚
6. Ascorbic Acid-Initiated Tandem Radical Cyclization of N-Arylacrylamides to Give 3,3-Disubstituted Oxindoles [O] . Sheng Liu, Pi Cheng, Wei Liu, 2015

机译：抗坏血酸引发的N-芳基丙烯酰胺串联自由基环化产生3,3-二取代氧吲哚

Copper promoted radical addition/cyclization of azobisisobutyronitrile with arylacrylamides: a convenient process to synthesize 3-(2 '-cyano alkyl) oxindoles

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