Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases

Tassi Marco; Bartollini Elena; Adriaensens Peter; Bianchi Luca; Barkakaty Balaka; Carleer Robert; Chen Jihua; Hensley Dale K.; Marrocchi Assunta; Vaccaro Luigi

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Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases

机译：新型大网络聚苯乙烯固定有机碱的合成，表征和催化活性

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In view of searching for efficient polymeric supports for organic bases to be used in environmentally friendly reaction conditions, novel gel-type cross-linked polystyrenes functionalized with diethylamine and 1,5,7-triazabicyclo[4.4.0]dec-5-ene, have been prepared. The structural properties and morphology of these catalysts have been determined by extensive solid state NMR experiments, FTIR spectroscopy and SEM/TEM microscopy. SPACeR-supported bases were found to exhibit high catalytic activity in the epoxide ring opening by phenols. A range of beta-substituted alcohols have been readily and regioselectively synthesized.

机译：考虑到寻找在环境友好的反应条件下使用的有机碱的有效聚合物载体，新型的用二乙胺和1,5,7-三氮杂双环[4.4.0] dec-5-ene官能化的凝胶型交联聚苯乙烯，已经准备好了。这些催化剂的结构性质和形态已通过广泛的固态NMR实验，FTIR光谱和SEM / TEM显微镜确定。发现SPACeR负载的碱在酚类化合物的环氧开环中表现出高催化活性。已经容易地和区域选择性地合成了许多β-取代的醇。

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《RSC Advances》 |2015年第130期|共9页
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Tassi Marco; Bartollini Elena; Adriaensens Peter; Bianchi Luca; Barkakaty Balaka; Carleer Robert; Chen Jihua; Hensley Dale K.; Marrocchi Assunta; Vaccaro Luigi;
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中图分类化学;
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1. Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases [J] . Tassi Marco, Bartollini Elena, Adriaensens Peter, RSC Advances . 2015,第130期

机译：新型大网络聚苯乙烯固定有机碱的合成，表征和催化活性
2. Synthesis and Characterization of Two Novel Organic-Inorganic Compounds Based on Tetrahexyl and Tetraheptyl Ammonium Ions and the Preyssler Anion and Their Catalytic Activities in the Synthesis of 4-Aminopyrazolo[3,4-d]- Pyrimidines [J] . Fatemeh Farrash Bamoharram Molecules . 2010,第4期

机译：两种新的基于四己基和四庚基铵离子和Preyssler阴离子的有机-无机化合物的合成，表征及其在4-氨基吡唑并[3,4-d]-嘧啶的合成中的催化活性
3. Two low-dimensional Schiff base copper(I/II) complexes: synthesis, characterization and catalytic activity for degradation of organic dyes [J] . Hong Xu-Jia, Liu Xiang, Zhang Jing-Bo, CrystEngComm . 2014,第34期

机译：两种低维席夫碱铜（I / II）配合物：有机染料的合成，表征和催化活性
4. Pd nanoparticles immobilized onto polymer-inorganic hybrid support: Synthesis, characterization and catalytic activity on Suzuki-Miyaura coupling reactions in water [C] . Minkyung Lim, Hyeji Kim, Yoorim Jang, Annual techconnect world innovation conference expo;Defense techconnect DTS conference;Annual nanotech conference expo;SBIR/STTR innovation conference . 2018

机译：固定在聚合物-无机杂化载体上的钯纳米颗粒：水中铃木-宫浦偶联反应的合成，表征和催化活性
5. Emergent Cooperative Behavior between Acid and Base Sites on Heterogeneous Catalysts: Synthesis, Characterization, and Catalytic Activity [D] . Young, Pria Derby 2013

机译：多相催化剂上酸和碱之间的紧急合作行为：合成，表征和催化活性。
6. Synthesis and Characterization of Two Novel Organic-Inorganic Compounds Based on Tetrahexyl and Tetraheptyl Ammonium Ions and the Preyssler Anion and Their Catalytic Activities in the Synthesis of 4-Aminopyrazolo34-d- Pyrimidines [O] . Fatemeh Farrash Bamoharram 2010

机译：两种新的基于四己基和四庚基铵离子和Preyssler阴离子的有机-无机化合物的合成表征及其在4-氨基吡唑并34-d-嘧啶的合成中的催化活性
7. Synthesis and Characterization of Two Novel Organic-Inorganic Compounds Based on Tetrahexyl and Tetraheptyl Ammonium Ions and the Preyssler Anion and Their Catalytic Activities in the Synthesis of 4-Aminopyrazolo[3,4-d]- Pyrimidines [O] . Fatemeh Farrash Bamoharram 2010

机译：基于四己基和四庚基铵离子及preyssler阴离子的两种新型有机 - 无机化合物的合成与表征及其在4-氨基吡唑并[3,4-d] - 嘧啶合成中的催化活性

Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases

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