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Copper(II) phthalocyanine supported on a three-dimensional nitrogen-doped graphene/PEDOT-PSS nanocomposite as a highly selective and sensitive sensor for ammonia detection at room temperature

机译:负载在三维氮掺杂石墨烯/ PEDOT-PSS纳米复合材料上的酞菁铜(II)作为高选择性和灵敏性传感器,可在室温下检测氨

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摘要

Here we present a highly efficient ammonia (NH3) gas sensor made of copper(II) tetrasulfophthalocyanine supported on a three-dimensional nitrogen-doped graphene based framework (CuTSPc@3D-(N)GF)/poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) nanocomposite sensing film with high uniformity over a large surface area. The NH3 gas sensing performance of the nanocomposite was compared with those of sensors based on pure PEDOT-PSS and a pristine CuTSPc@3D-(N) GF. It was revealed that the synergistic behavior between both of these candidates allowed excellent sensitivity and selectivity for NH3 gas in a low concentration range of 1-1000 ppm at room temperature. The CuTSPc@3D-(N) GF/PEDOT-PSS nanocomposite gas sensor exhibited a much better response (similar to 5 and 53 times, with a concentration of NH3 gas at 200 ppm) to NH3 gas than those of the pure PEDOT-PSS and pristine CuTSPc@3D-(N) GF gas sensors, respectively. The combination of the CuTSPc@ 3D-(N) GF and PEDOT-PSS facilitated the enhancement in the sensing properties of the final nanocomposite and paved a new avenue for the application of CuTSPc@3D-(N) GF/PEDOT-PSS nanocomposites in the gas sensing field.
机译:在这里,我们介绍了一种高效的氨(NH3)气体传感器,该传感器由四硫代酞菁铜(II)铜制成,并支撑在基于三维氮掺杂的石墨烯的骨架上(CuTSPc @ 3D-(N)GF)/聚(3,4-乙撑二氧噻吩) -聚(苯乙烯磺酸盐)(PEDOT-PSS)纳米复合材料传感膜,在大表面积上具有较高的均匀性。将纳米复合材料中的NH3气敏性能与基于纯PEDOT-PSS和原始CuTSPc @ 3D-(N)GF的传感器进行了比较。揭示了这两种候选物之间的协同行为使得在室温下在1-1000 ppm的低浓度范围内对NH3气体具有出色的灵敏度和选择性。 CuTSPc @ 3D-(N)GF / PEDOT-PSS纳米复合气体传感器对NH3气体的响应比纯PEDOT-PSS更好(接近5倍和53倍,NH3浓度为200 ppm)和原始CuTSPc @ 3D-(N)GF气体传感器。 CuTSPc @ 3D-(N)GF和PEDOT-PSS的组合促进了最终纳米复合材料的传感性能的增强,并为CuTSPc @ 3D-(N)GF / PEDOT-PSS纳米复合材料的应用铺平了新途径。气体传感领域。

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