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Simultaneous adsorption of Cd2+ and reactive dye on mesoporous nanocarbons

机译:Cd2 +和活性染料在中孔纳米碳上的同时吸附

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High-surface-area mesoporous MgO-templated nanocarbons made with reinforcing fibres from scrap tyres and a bituminous waste as carbon precursors were employed for the simultaneous adsorption of Cd2+ and reactive Cibacron Brilliant Yellow 3G-P dye. A commercial activated carbon (AC) Darco KB-WJ was also used for comparison purposes. The effect of the pH of the solution was studied to establish whether acidic pH favours the adsorption of reactive dye and alkaline pH improves the removal of Cd2+. Because the surface chemistry of the three adsorbents was similar, the focus in this study was directed towards their textural characteristics. It was found that the larger the S-BET, the greater the amount of dye removal. The adsorption isotherms corresponding to the commercial AC fitted to the Langmuir-Freundlich model, whereas in the case of the nanocarbons the Langmuir model provided the best fit. The results obtained show that Cd2+ is successfully adsorbed in the presence of the dye due to the ion exchange between the Na+ from the dye and the Cd2+. It was also found that a high total and mesopore volume, and a high S-BET played a determinant role in the simultaneous adsorption.
机译:使用由废轮胎的增强纤维和沥青废物作为碳前体制备的高表面积介孔MgO模板纳米碳,用于同时吸附Cd2 +和活性Cibacron亮黄3G-P染料。商用活性炭(AC)Darco KB-WJ也用于比较。研究了溶液pH的影响,以确定酸性pH是否有利于活性染料的吸附,而碱性pH是否可以改善Cd2 +的去除。由于三种吸附剂的表面化学性质相似,因此本研究的重点是针对其质地特征。发现S-BET越大,染料去除量越大。吸附等温线对应于适用于Langmuir-Freundlich模型的商用AC,而在纳米碳的情况下,Langmuir模型提供了最佳拟合。所得结果表明,由于存在于染料中的Na +与Cd2 +之间发生了离子交换,因此Cd2 +在染料存在下被成功吸附。还发现高的总和中孔体积以及高的S-BET在同时吸附中起决定性作用。

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