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首页> 外文期刊>RSC Advances >A green approach to crosslinked polymer microspheres with undoped methacrylate monomers and their potential application as dental restorative materials
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A green approach to crosslinked polymer microspheres with undoped methacrylate monomers and their potential application as dental restorative materials

机译：一种未掺杂甲基丙烯酸酯单体交联聚合物微球的绿色方法及其在牙科修复材料中的潜在应用

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Herein, a green approach to crosslinked polymer microspheres with undoped methacrylate monomers is presented. The protocol is set up by means of photoinitiated precipitation polymerization of a trifunctional crosslinker, i.e. trihydroxymethyl propane trimethyl acrylate (TMPTMA) and methyl methacrylate (MMA) for the purpose of achieving pure and crosslinked microspheres. The evolution of photoinitiated precipitation polymerization is tracked and the formation mechanism of poly(TMPTMA-MMA) microspheres is also elucidated. Finally, the potency of so-obtained crosslinked microspheres is explored to serve as organic fillers in dental restorative materials.
机译：在此，提出了一种绿色方法，用于与未掺杂的甲基丙烯酸酯单体交联的聚合物微球。为了实现纯的和交联的微球，通过三官能交联剂，即三羟甲基丙烷三丙烯酸甲酯（TMPTMA）和甲基丙烯酸甲酯（MMA）的光引发沉淀聚合来建立该方案。跟踪了光引发沉淀聚合反应的演变，并阐明了聚（TMPTMA-MMA）微球的形成机理。最后，探索了如此获得的交联微球的效力，以在牙科修复材料中用作有机填充剂。

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