Metal-free in situ sp(3), sp(2), and sp C-H functionalization and oxidative cross coupling with benzamidines hydrochloride: a promising approach for the synthesis of alpha-ketoimides

Kalmode Hanuman P.; Vadagaonkar Kamlesh S.; Chaskar Atul C.

首页> 外文期刊>RSC Advances >Metal-free in situ sp(3), sp(2), and sp C-H functionalization and oxidative cross coupling with benzamidines hydrochloride: a promising approach for the synthesis of alpha-ketoimides

【24h】

Metal-free in situ sp(3), sp(2), and sp C-H functionalization and oxidative cross coupling with benzamidines hydrochloride: a promising approach for the synthesis of alpha-ketoimides

机译：无金属的原位sp（3），sp（2）和sp C-H功能化以及与盐酸苄nz的氧化交叉偶联：合成α-酮亚胺的有前途的方法

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new metal-free tandem protocol for the synthesis of alpha-ketoimides via sp(3), sp(2), and sp C-H functionalization followed by oxidative cross coupling with benzamidines hydrochloride using catalytic iodine with TBHP in DMSO has been developed. A wide range of functional group tolerance, an inexpensive catalyst, operational simplicity and good to excellent yields of the products are the striking features of this method.

机译：已经开发了一种新的无金属串联方案，用于通过sp（3），sp（2）和sp C-H官能化合成α-酮酰亚胺，然后在DMSO中使用催化碘和TBHP与苯甲chlor盐酸盐进行氧化交叉偶联。该方法的显着特征是具有宽泛的官能团耐受性，廉价的催化剂，操作简便以及产物的产率高至优异。

著录项

来源
《RSC Advances》 |2014年第104期|共11页
作者
Kalmode Hanuman P.; Vadagaonkar Kamlesh S.; Chaskar Atul C.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Metal-free in situ sp(3), sp(2), and sp C-H functionalization and oxidative cross coupling with benzamidines hydrochloride: a promising approach for the synthesis of alpha-ketoimides [J] . Kalmode Hanuman P., Vadagaonkar Kamlesh S., Chaskar Atul C. RSC Advances . 2014,第104期

机译：无金属的原位sp（3），sp（2）和sp C-H功能化以及与盐酸苄nz的氧化交叉偶联：合成α-酮亚胺的有前途的方法
2. Molecular iodine mediated oxidative cross-coupling of sp(3) C-H with sp(2) C-H: direct synthesis of substituted indolo[2,3-b]carbazoles via formal [2+2+1+1] cyclization [J] . Xue Wei-jian, Gao Qing-He, Wu An-xin Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第51期

机译：sp（3）C-H与sp（2）C-H的分子碘介导的氧化交叉偶联：通过正式的[2 + 2 + 1 + 1]环化反应直接合成取代的吲哚[2,3-b]咔唑
3. Iron-Mediated Oxidative C-H Alkylation of S,S-Functionalized Internal Olefins via C(sp(2))-H/C(sp(3))-H Cross-Coupling [J] . Wang Quannan, Lou Jiang, Wu Ping, Advanced synthesis & catalysis . 2017,第17期

机译：铁介导的S，S官能化内烯烃的氧化C-H烷基化（SP（2）） - H / C（SP（3）） - H交叉耦合
4. Ni/Co-Catalyzed C(sp~3)-C(sp~3) Cross-Coupling Using Alkyl Tosylates as Radical Sources [C] . Takuya Michiyuki, Itaru Osaka, Kimihiro Komeyama 日本化学会春季年会講演予稿集 . 2018

机译：Ni /助催化的C（SP〜3）-C（SP〜3）使用烷基甲磺酸盐作为自由基来源的交叉偶联
5. Iron-catalyzed decarboxylative cross coupling reactions and palladium-catalyzed sp2-sp3 coupling of coumarins [D] . Trivedi, Rushi 2009

机译：铁催化香豆素的脱羧交叉偶联反应和钯催化的sp2-sp3偶联
6. C-H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3 C-H Bonds Catalyzed by Platinum Tetraiodide [O] . Paul A. Vadola, Dalibor Sames -1

机译：通过氢转移C-H键功能化：未激活炔烃的直接耦合和sp3 C-H键的催化作用白金四碘化物
7. Metal-Free sp3 C-H Bond Oxidation and Functionalization of α-Bromoketones to Quinoxalinone, Benzoxazinone, and Benzothiazinone Heterocyclic Compounds [O] . Xiuling Chen, Fang Guo, Tianlong Wei, 2021

机译：无金属SP3 C-H键氧化和α-溴代酮，苯并嗪酮和苯并噻嗪酮杂环化合物的官能化

Metal-free in situ sp(3), sp(2), and sp C-H functionalization and oxidative cross coupling with benzamidines hydrochloride: a promising approach for the synthesis of alpha-ketoimides

摘要

著录项

相似文献

相关主题

期刊订阅