Efficient access to polysubstituted tetrahydrofurans by electrophilic cyclization of vinylsilyl alcohols

Barbero Asuncion; Barbero Hector; Gonzalez-Ortega Alfonso; Pulido Francisco J.; Val Patricia; Diez-Varga Alberto; Moran Joaquin R.

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Efficient access to polysubstituted tetrahydrofurans by electrophilic cyclization of vinylsilyl alcohols

机译：通过乙烯基硅醇的亲电环化有效获得多取代的四氢呋喃

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Vinylsilyl alcohols undergo intramolecular cyclization to provide di-, tri- or tetrasubstitutedtetrahydrofurans. The influence of the number and position of substituents in the stereoselectivity of the process has been studied. Moreover, DFT calculations have been performed to get better insight into the influence of the substitution pattern of the vinylsilyl alcohol in the stereoselectivity of the cyclization.

机译：乙烯基硅烷醇经历分子内环化以提供二，三或四取代的四氢呋喃。已经研究了取代基的数目和位置在该方法的立体选择性中的影响。而且，已经进行了DFT计算以更好地了解乙烯基硅烷醇的取代模式对环化的立体选择性的影响。

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《RSC Advances》 |2015年第61期|共11页
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Barbero Asuncion; Barbero Hector; Gonzalez-Ortega Alfonso; Pulido Francisco J.; Val Patricia; Diez-Varga Alberto; Moran Joaquin R.;
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正文语种 eng
中图分类化学;
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1. Efficient access to polysubstituted tetrahydrofurans by electrophilic cyclization of vinylsilyl alcohols [J] . Barbero Asuncion, Barbero Hector, Gonzalez-Ortega Alfonso, RSC Advances . 2015,第61期

机译：通过乙烯基硅醇的亲电环化有效获得多取代的四氢呋喃
2. Mild and efficient copper-catalyzed oxidative cyclization of oximes with 2-aminobenzyl alcohols at room temperature: synthesis of polysubstituted quinolines [J] . Yan-Yun Liu, Yang Wei, Zhi-Hui Huang, Organic & biomolecular chemistry . 2021,第3期

机译：在室温下用2-氨基苄醇的温和和高效的铜催化的氧化氧化环化：聚合物喹啉的合成
3. AlCl3-PROMOTED CYCLIZATION OF beta-KETO DERIVATIVES WITH IN SITU GENERATED ENAMINES UNDER SOLVENT-FREE HIGH SPEED BALL MILLING: AN EFFICIENT ONE-POT ACCESS TO POLYSUBSTITUTED 1,4-DIHYDROPYRIDINES [J] . Zeng Ji-Chao, Yu Fei, Asiri Abdullah M., Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2017,第11期

机译：在无溶剂高速球铣削下促进β-酮衍生物的β-酮衍生物的环化：有效的一罐对多助化1,4-二氢吡啶的含量
4. A Convenient Synthetic Approach to Five-membered Heterocyclic Compounds by Electrophilic 5-Endo-trig Cyclization Reactions of Bifunctionalized Allenes [C] . Valerij Ch. Christov, Jordanka G. Ivanova, Boris Prodanov European Symposium on Organic Chemistry . 2009

机译：通过双官能化甲烯的亲电5- endo-TrIG环化反应的五元杂环化合物的方便合成方法
5. Novel C-X/C-X bond formations using 1,3-dicarbonyls and their derivatives in the synthesis of polysubstituted heterocycles. [D] . Roslan, Irwan Iskandar bin. 2016

机译：在多取代杂环的合成中，使用1,3-二羰基及其衍生物形成新的C-X / C-X键。
6. Highly Diastereoselective Pd-Catalyzed Carboetherification Reactions of Acyclic Internal Alkenes. Stereoselective Synthesis of Polysubstituted Tetrahydrofurans [O] . Amanda F. Ward, John P. Wolfe -1

机译：非循环内部烯的高立体选择性钯催化反应Carboetherification。多取代四氢呋喃的立体选择性合成
7. General 4 + 1 Cyclization Approach To Access 2,2-Disubstituted Tetrahydrofurans Enabled by Electrophilic Bifunctional Peroxides [O] . -1

机译：一般4 + 1循环化方法，用于进入电泳双官能过氧化物使能的2,2-二取代的四氢呋喃

Efficient access to polysubstituted tetrahydrofurans by electrophilic cyclization of vinylsilyl alcohols

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