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Synthesis and characterisation of layered double hydroxide dispersions in organic solvents

机译:有机溶剂中层状双氢氧化物分散体的合成与表征

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Aqueous Miscible Organic Solvent Treatment (AMOST) Mg3AlCO3-LDHs have been prepared using twelve different (AMO) solvents. We find that the AMOST process produces significant changes to the crystallinity, morphology, thermal behaviour and dramatically increases the surface areas of the LDHs compared to conventional LDHs. Remarkably AMO-LDHs platelets are now hydrophobic and can be dispersed in a range of organic liquids. Clear dispersions of AMO-Mg3AlCO3-LDHs are observed in aromatic solvents. Overall, we found that the optimum AMO-Mg3AlCO3-LDHs organic solvent dispersions are obtained using 1-propanol as a treating solvent and ethyl benzene as the dispersion solvent. This system produces a monophasic dispersion at loading up to 140 g L-1 of Mg3AlCO3-LDH in ethyl benzene. At a maximum loading of 160 g L-1 Mg3AlCO3-LDH this mixture becomes a thick monophasic gel.
机译:水溶性有机溶剂处理(AMOST)已使用十二种不同(AMO)溶剂制备了Mg3AlCO3-LDH。我们发现,与传统的LDH相比,AMOST工艺对结晶度,形态,热行为产生了重大变化,并大大增加了LDH的表面积。现在,AMO-LDHs血小板非常疏水,可以分散在多种有机液体中。在芳族溶剂中观察到AMO-Mg3AlCO3-LDHs的透明分散体。总的来说,我们发现使用1-丙醇作为处理溶剂,使用乙苯作为分散溶剂可以得到最佳的AMO-Mg3AlCO3-LDHs有机溶剂分散体。该系统在乙苯中负载多达140 g L-1的Mg3AlCO3-LDH时会产生单相分散体。在最大装载量为160 g L-1 Mg3AlCO3-LDH时,该混合物变成浓稠的单相凝胶。

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