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On the chiroptical properties of Au(I)-thiolate glycoconjugate precursors and their influence on sugar-protected gold nanoparticles (glyconanoparticles)

机译:关于Au(I)-硫醇盐糖缀合物前体的手性及其对糖保护的金纳米颗粒(糖基纳米颗粒)的影响

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摘要

Chiral gold nanoparticles passivated with glycoconjugates were prepared. By extensive washing, they lost their chiroptical activity, whereas highly luminescent compounds isolated from the washing reproduced the original ellipticity. A systematic characterization of these compounds, Au(I) precursors and glyconanoparticles allowed us to unravel the origin of the observed chiroptical activity.
机译:制备了用糖缀合物钝化的手性金纳米颗粒。通过大量洗涤,它们失去了其按摩作用,而从洗涤中分离出的高发光化合物则恢复了原始的椭圆度。对这些化合物,Au(I)前体和糖纳米颗粒的系统表征使我们能够阐明所观察到的按摩疗法活动的起源。

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