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Molecular design of the amphiphilic AB diblock copolymer toward one-step synthesis of amino-group functionalized large pore mesoporous silica

机译:两性AB二嵌段共聚物的一步一步合成氨基官能化大孔介孔二氧化硅的分子设计

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摘要

Amino group functionalized mesoporous silica with large pore size was obtained by one-step self-assembly of an amphiphilic AB diblock copolymer containing a hydrophobic poly(styrene) (PS) tail and a hydrophilic poly(acrylic acid) (PAA) head, a co-structure directing agent (CSDA) and a silica source. The mesoporous silica possessed hexagonal arranged ordered channels with large pore size of ca. 27.5 nm, and 3.1 mmol g(-1) amino group loading amount.
机译:通过两步性两亲AB二嵌段共聚物的一步自组装,该两官能团AB具有疏水性聚苯乙烯(PS)尾部和亲水性聚丙烯酸(PAA)头,一个可结构导向剂(CSDA)和二氧化硅源。介孔二氧化硅具有六边形排列的有序通道,其大孔尺寸约为。 27.5 nm和3.1 mmol g(-1)氨基负载量。

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