Syntheses of selenoesters through C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions

Liou Jyun-Cyuan; Badsara Satpal Singh; Huang Yu-Ting; Lee Chin-Fa

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Syntheses of selenoesters through C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions

机译：在无金属和无溶剂条件下通过醛与二硒化物的C-H硒化硒化酯的合成

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A DTBP-promoted C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions is described. This system shows good functional group compatibility, functional groups including bromo, trifluoromethyl, chloro, amine and heterocycle-containing moieties including thiophene and furan are all tolerated by the reaction conditions employed. Both diaryl and dialkyl diselenides reacted smoothly with aldehydes to provide selenoesters in good to excellent yields.

机译：描述了在无金属和无溶剂条件下DTBP促进的醛与二硒化物的C-H硒化。该系统显示出良好的官能团相容性，所采用的反应条件可耐受包括溴，三氟甲基，氯，胺和含杂环的部分（包括噻吩和呋喃）在内的官能团。二芳基和二烷基二硒化物均与醛顺利反应，从而以良好或优异的产率提供硒酸酯。

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《RSC Advances》 |2014年第78期|共8页
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Liou Jyun-Cyuan; Badsara Satpal Singh; Huang Yu-Ting; Lee Chin-Fa;
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中图分类化学;
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1. Syntheses of selenoesters through C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions [J] . Liou Jyun-Cyuan, Badsara Satpal Singh, Huang Yu-Ting, RSC Advances . 2014,第78期

机译：在无金属和无溶剂条件下通过醛与二硒化物的C-H硒化硒化酯的合成
2. Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions [J] . Jing-Wen Zeng, Yi-Chen Liu, Ping-An Hsieh Green chemistry . 2014,第5期

机译：DTBP作为氧化剂在无溶剂条件下醛与二硫化物的无金属交叉偶联反应
3. Metal-Free Greener Syntheses of Pyrimidine Derivatives Using a Highly Efficient and Reusable Graphite Oxide Carbocatalyst under Solvent-Free Reaction Conditions [J] . Binoyargha Dam, Ramen Jamatia, Ajay Gupta, ACS Sustainable Chemistry & Engineering . 2017,第12期

机译：在无溶剂反应条件下，使用高效可重复使用的石墨氧化物碳酸含有高效且可重复使用的石墨氧化物的无金属格兰德衍生物
4. Manganese-Catalyzed Insertion of an Aldehyde into a C-H Bond [C] . Yuta Nishina, Takahiro Takeuchi, Yoichiro Kuninobu Symposium on Organometallic Chemistry . 2007

机译：锰催化剂将醛插入C-H键
5. I. Solvent-free oxidation of primary ARYL alcohols to aldehydes, and, II. Conversion of primary amide to nitrile using silicon tetrachloride as the dehydrating agent. [D] . Pedraza, Fernando. 2006

机译：I.芳族伯醇无溶剂氧化为醛，以及II。使用四氯化硅作为脱水剂将伯酰胺转化为腈。
6. Synthesis and anticancer activity of bis(2-arylimidazo12-apyridin-3-yl) selenides and diselenides: the copper-catalyzed tandem C–H selenation of 2-arylimidazo12-apyridine with selenium [O] . Mio Matsumura, Tsutomu Takahashi, Hikari Yamauchi, 2020

机译：双（2- arylimidazo 12-a吡啶-3-基）硒化物和二烯醇的合成和抗癌活性：2-芳基咪唑与硒的铜催化的串联C-H硒化酶12-a吡啶
7. Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions [O] . Zeng Jing-Wen, Liu Yi-Chen, Hsieh Ping-An, 2015

机译：metal-free cross-coupling reaction of aldehydes with disulfides by using DTBp as an oxidant under solvent-free conditions

Syntheses of selenoesters through C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions

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