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Ionic liquid/water mixture promoted organic transformations

机译:离子液体/水混合物促进了有机转化

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Ionic liquids (ILs) have been used in numerous applications in chemistry. Wet ILs constitute a new class of solvents with their own new and interesting properties. The properties of ILs are significantly influenced by the addition of water and also affect reaction rates and selectivity. IL/water mixing makes it easy to control the properties of the solution and the formation of these ionic liquid mixtures increases synthetic flexibility. In this review, mixtures of IL/water solvent system promoted organic reactions have been described and the results are compared with other solvent systems. In many cases IL/water combinations were superior compared to conventional organic solvents and biphasic IL/organic co-solvent media with respect to catalytic performance as well as to catalyst separation and recycling.
机译:离子液体(ILs)已用于化学领域的众多应用中。湿式离子液体构成一类新的溶剂,它们具有自己独特的新特性。 IL的性质受水的添加影响很大,并且还会影响反应速率和选择性。 IL /水混合使控制溶液的特性变得容易,这些离子液体混合物的形成增加了合成的灵活性。在这篇综述中,描述了由IL /水溶剂体系促进的有机反应的混合物,并将结果与​​其他溶剂体系进行了比较。在许多情况下,就催化性能以及催化剂的分离和循环利用而言,IL /水的组合优于常规有机溶剂和双相IL /有机助溶剂。

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