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Facile identification of the critical content of multi-layer graphene oxide for epoxy composite with optimal thermal properties

机译:轻松识别具有最佳热性能的环氧复合材料中多层氧化石墨烯的临界含量

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摘要

Multi-layer graphene oxide (MGO) has attracted considerable interest in conductive polymer composites. However, in most cases the optimal MGO content is determined using a complex procedure. Avoiding the complicated work of processing polymerized samples followed by testing various properties, here a facile strategy is proposed to directly identify the critical MGO content among formulations for epoxy composites with optimal thermal properties, simply by monitoring the "unusual" nonlinear MGO content-dependent cure behaviors, as well as the "unusual" pattern of double-peak curing curves. The formation mechanism of the double-peak pattern was explored, with emphasis on studying the epoxy/MGO reaction using a modified Shrinking Core Model. The optimal content determined in this work 2 wt% MGO) was verified by the thermal properties (thermal conductivity, structural thermal stability and coefficient of thermal expansion) of MGO/epoxy composites. Based on the inherent relationship between the effect of MGO percolating chains on the thermal polymerization behavior and the resulting thermal properties, this strategy can be easily extended to different kinds of conductive MGO/polymer composites.
机译:多层氧化石墨烯(MGO)在导电聚合物复合材料中引起了相当大的兴趣。但是,在大多数情况下,最佳MGO含量是使用复杂的过程确定的。避免了处理聚合样品并随后测试各种性能的繁琐工作,这里提出了一种简便的策略,只需监测“异常”的非线性MGO含量依赖性固化,即可直接确定具有最佳热性能的环氧复合材料配方中的关键MGO含量。行为以及双峰固化曲线的“异常”模式。探索了双峰图形的形成机理,重点是使用改进的收缩核心模型研究环氧/ MGO反应。通过MGO /环氧树脂复合材料的热性能(导热系数,结构热稳定性和热膨胀系数)验证了在这项工作中确定的最佳含量(2 wt%MGO)。基于MGO渗流链对热聚合行为的影响与所得热特性之间的固有关系,该策略可以轻松地扩展到不同种类的导电MGO /聚合物复合材料。

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