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Novel nanostructured LiMn2O4 microspheres for high power Li-ion batteries

机译:用于高功率锂离子电池的新型纳米结构LiMn2O4微球

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摘要

A novel type of nanostructured LiMn2O4 microsphere was successfully synthesized by wet ball milling combined with high-temperature calcinations. The prepared materials were characterized by XRD, SEM, BET surface area measurement, electrochemical galvanostatic cycling tests, EIS, and XRF. The results show that the well-shaped microspheres with a diameter of approximately 0.5-2 mu m are composed of reorganized nanoparticles. The LiMn2O4 microspheres have a high tap density of 2.8 g cm(-3), and as electrodes, these micro/ nanostructured spheres show excellent rate capability and cycle stability, resulting in a high volumetric energy density, even at elevated temperature. These materials are promising for power battery applications.
机译:通过湿球磨结合高温煅烧成功地合成了新型的纳米结构的LiMn2O4微球。通过XRD,SEM,BET表面积测量,电化学恒电流循环测试,EIS和XRF对制备的材料进行表征。结果表明,直径约0.5-2μm的形状良好的微球由重组的纳米颗粒组成。 LiMn2O4微球具有2.8 g cm(-3)的高振实密度,并且作为电极,这些微/纳米结构球显示出极好的速率能力和循环稳定性,即使在高温下也具有高体积能量密度。这些材料有望用于动力电池。

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